Is Earth’s Core Rusting? A close view of rush on iron. Photo: Laitr Keiows/Wikimedia Commons, CC BY-SA 4.0 Source: (https://bit.ly/3M5oMJZ) -Deep below Earth’s surface – 2,900 km deep, to be precise is a mass of mostly molten iron forming the planet’s outer core. Could it rust as well? -Scientists have recently shown that when iron meets moisture at pressures close to 1 million atmospheres, the oxidation reaction can form high-pressure rust. -If rust is actually present where the outer core meets the mantle, scientists may need to update their view of Earth’s interior and its history. -This rust could shed light on the deep-water cycle in the lower mantle and on the enigmatic origins of small, thin regions atop Earth’s fluid core that slow seismic waves. -It could also help answer questions about the beginning of Earth’s oxygen-rich atmosphere and how the atmospheric free oxygen level reached the level of today. Iron on Earth’s surface – whether in simple nails or mighty girders reacts gradually when exposed to moist air or oxygenated water through a chemical reaction known as oxidation. The reddish-brown product of this reaction, rust, can consist of various forms of hydrous (water-bearing) iron oxides and iron oxide-hydroxide materials. In nature, the red rocks found in arid climes similarly owe their color to the iron oxide mineral hematite, whereas in wetter environments, iron ore minerals like hematite weather to form the iron oxide-hydroxide mineral goethite (FeOOH). Deep below Earth’s surface – 2,900 km deep, to be precise is a mass of mostly molten iron forming the planet’s outer core. Could it rust as well? In experiments, scientists have recently shown that when iron meets moisture – as water or in the form of hydroxyl-bearing minerals at pressures close to 1 million atmospheres, similar to pressures in the deep lower mantle, it forms iron peroxide or a high-pressure form of iron oxide-hydroxide with the same structure as pyrite (i.e., pyrite-type FeOOH) [Hu et al., 2016, Mao et al., 2017]. In other words, the oxidation reactions in these experiments do, indeed, form high-pressure rust.