[HN Gopher] Bio-coal: A renewable and producible fuel from ligno...
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       Bio-coal: A renewable and producible fuel from lignocellulosic
       biomass
        
       Author : rch
       Score  : 63 points
       Date   : 2020-01-05 16:50 UTC (6 hours ago)
        
 (HTM) web link (advances.sciencemag.org)
 (TXT) w3m dump (advances.sciencemag.org)
        
       | semi-extrinsic wrote:
       | Bio-coal is possible, and may be economically viable (especially
       | when produced from biowaste as here), but only makes sense for an
       | extremely brief transition window. So these guys need to go from
       | the current five-gram scale to the estimated one million tonnes
       | per day scale in less than five years. Maybe in China that's
       | possible.
        
         | elric wrote:
         | I'm not sure whether I agree with your timeline. Coal will
         | likely remain useful for a variety of industrial processes,
         | like steel production.
        
           | MertsA wrote:
           | Even with steel there's direct reduced iron and electrolytic
           | steel production is already on the horizon.
        
             | neltnerb wrote:
             | Is this what you're talking about?
             | 
             | https://www.scientificamerican.com/article/cleaner-
             | cheaper-w...
             | 
             | Looks like another great way to use excess renewable power
             | when the grid is underutilized but the wind is blowing and
             | the sun is shining. Build enough of these to matter and you
             | could probably get away with a fair bit less battery
             | storage as long as you still have natural gas peakers.
        
               | jacobush wrote:
               | http://www.hybritdevelopment.com
               | 
               |  _" If successful, HYBRIT means that together we can
               | reduce Sweden's CO2 emissions by 10% and Finland's by
               | 7%."_
        
               | neltnerb wrote:
               | Nice! I saw a great presentation from some researchers
               | that figured out how to make electrolytic Boron as well
               | using molten oxide electrolysis.
               | 
               | http://dspace.mit.edu/bitstream/handle/1721.1/64889/34540
               | 560... (warning, link to a thesis)
        
               | jacobush wrote:
               | How old are you? ;-)
        
               | neltnerb wrote:
               | Why?
        
               | jacobush wrote:
               | _" I saw a great presentation from some researchers  "_
               | and the paper you linked to was from 1940. :-)
        
           | pjc50 wrote:
           | Before coal, there was charcoal; the process works perfectly
           | well with it. We switched because the energy-ROI and
           | logistics are much easier than the manual charcoal production
           | process was.
        
           | neltnerb wrote:
           | But that's because of it's usefulness as a chemical precursor
           | (i.e. carbon) rather than because it was worth it to burn for
           | straight heating energy in a power plant.
           | 
           | I am pretty much okay with (or at least resigned to)
           | petrochemicals/coal being used for the next 30 years to
           | produce chemicals and other products. _Burning_ it is a waste
           | of a very useful chemical feedstock.
           | 
           | The lowest value (and by extension least valuable) thing you
           | can do with a material like coal is burn it. If it's used
           | because of it's properties _other_ than it 's fuel content of
           | course it's value is higher and economics will make it more
           | compelling. These are entirely different markets in size and
           | kind.
        
       | acvny wrote:
       | Although biofuels prevent consumption of fossil fuels, they still
       | contribute to CO2 emmissions. Another side effect is that the
       | land resources used to grow those biofuels are consumed. Also
       | they lead to food prices increase and shortages. The good thing
       | is when the raw material is made of leftovers from normal food
       | oriented farming. However when farmers replace corn cultures with
       | rapeseed that's bad.
        
         | doctor_eval wrote:
         | This doesn't make sense to me.
         | 
         | First, the CO2 released from burning farmed plants does not
         | increase the CO2 in the atmosphere. It's a cycle.
         | 
         | Second, climate change will also cause food prices to increase.
         | There is going to be an equilibrium point at which the
         | increased cost of food due to land use changes outweighs the
         | benefit of reduced emissions, but that point is almost
         | certainly not zero.
         | 
         | In theory, farmers could replace corn with rapeseed at no cost
         | to consumers if doing so mitigates climate change, the main
         | problem is that the net cost of doing so needs to be averaged
         | out over decades :(
        
         | oconnore wrote:
         | That's exactly why newer biofuels rely on sources that don't
         | require high investment crop land -- e.g. switchgrass and other
         | "weeds". You could also plant switchgrass in highway medians,
         | for example.
        
       | jacknews wrote:
       | Just charcoal the biowaste, and bury it.
       | 
       | Much less tech needed, and it actually reduces co2 not just
       | circulates it.
       | 
       | Profit is via increased crop yields.
        
         | ZeroGravitas wrote:
         | The paper talks about this option (well, burying the output of
         | this process).
         | 
         | It's carbon negative to use it as a soil additive, but you
         | don't get to burn the bio-coal for energy, so it's slightly
         | less profitable.
         | 
         | I guess you could do a bit of both and be exactly carbon
         | neutral.
        
         | swiley wrote:
         | If it's prepared with renewable/carbon neutral processes then
         | using it to generate heat will be renewable/carbon neutral. If
         | it's used to replace petrochemicals instead of heat (which they
         | pointed out was uneconomical anyway) it sequesters carbon, so
         | it's a good thing.
         | 
         | It's always better to have options.
        
         | [deleted]
        
         | zozbot234 wrote:
         | Bio-coal is charcoal, just produced by different means than
         | charring the biomass. Typically, bio-coal production manages to
         | convert more of the carbon into coal, while less of it is
         | burned.
        
           | samatman wrote:
           | Fairly sure GP's point was that sequestering the resulting
           | carbon is a better move than burning it back into the
           | atmosphere.
           | 
           | Meeting CO2 goals requires removing carbon actively from the
           | atmosphere, and drastically reducing our use of CO2-producing
           | energy sources. Burning bio-coal does neither of these
           | things; burying it accomplishes the former, and is at least
           | not working against the latter.
        
             | barry-cotter wrote:
             | > Meeting CO2 goals requires removing carbon actively from
             | the atmosphere, and drastically reducing our use of
             | CO2-producing energy sources.
             | 
             | No. Either one could be sufficient alone, just as you can
             | lose weight either by exercising more or eating less alone,
             | though generally the combination is better.
             | 
             | For removing carbon from the atmosphere we could dump
             | olivine sand into coastal waters where it would sequester
             | carbon as it was weathered. If we want to reduce our use of
             | CO2 producing energy sources without massive declines in
             | quality of life or vast environmental damage there's only
             | one choice, nuclear.
        
               | jointpdf wrote:
               | > _If we want to reduce our use of CO2 producing energy
               | sources without massive declines in quality of life or
               | vast environmental damage there's only one choice,
               | nuclear._
               | 
               | Unsubstantiated claim detected.
               | 
               | Solar, wind, hydroelectric, and geothermal are all
               | cheaper than nuclear (and even coal) for new generation
               | capacity. That includes capital, operation and
               | maintenance, and transmission costs. See tables starting
               | on page 8 for the numbers (https://www.eia.gov/outlooks/a
               | eo/pdf/electricity_generation....).
        
               | Krssst wrote:
               | What about storage cost to make it viable for base load?
        
               | Gibbon1 wrote:
               | In that vein I reduced the amount of CO2 my car produced
               | per year by one simple trick. I moved closer to work. I
               | was commuting 8000 miles a year. Now I'm commuting 4000
               | miles. And it's 10 minutes to work instead of 30.
        
               | barry-cotter wrote:
               | Solar requires the clearing of huge amounts of land, with
               | the associated destruction of wildlife. To the best of my
               | knowledge there has been no progress made in figuring out
               | what to do with solar panels at the end of their working
               | lives either and they all use lots of toxic heavy metals.
               | Wind doesn't leave lots of toxic waste but it does kill
               | millions of birds and bats a year, disproportionately
               | effecting large birds with long generation times, most of
               | which are predators like eagles. Hydroelectric is at
               | least less soul crushingly ugly but the environmental
               | effects of flooding huge amounts of land are hardly
               | positive. It's also basically played out in developed
               | countries. All of the suitable sites for hydroelectric
               | power have been developed. Besides turning mountain
               | ecosystems into lakes HEP is hideously dangerous in ways
               | that are basically unavoidable. The failures of the
               | Banqiao and Shimantan Dams killed 170-230K people in
               | 1971[1]
               | 
               | Solar, wind and hydro all entail a lot of damage to the
               | environment, far more than is necessary from nuclear,
               | just because they require much greater areas as they're
               | less energy dense.
               | 
               | I don't deny that nuclear is more expensive on those
               | grounds. I just think that relative safety is more
               | important. So by the most expansive counts Chernobyl
               | killed 4,000[2] people while air pollution kills about 7
               | million a year, every year[3]. Germany's closing of its
               | nuclear power plants has lead to an additional 1,000
               | deaths a year[4]
               | 
               | Nuclear is safer than any alternative source of energy,
               | wind, solar and hydro included. If you include those
               | costs nuclear looks amazing in comparison[6].
               | 
               | [1]https://en.wikipedia.org/wiki/Banqiao_Dam
               | 
               | [2]https://ourworldindata.org/what-was-the-death-toll-
               | from-cher...
               | 
               | [3]https://www.who.int/mediacentre/news/releases/2014/air
               | -pollu...
               | 
               | [4]https://www.washingtonexaminer.com/policy/energy/germa
               | n-nucl...
               | 
               | [5]http://papers.nber.org/tmp/26395-w26598.pdf
               | 
               | [6]https://www.statista.com/statistics/494425/death-rate-
               | worldw...
        
               | Certhas wrote:
               | Nuclear solves nothing. It has its role as a stop gap but
               | renewables are cheaper safer and easier.
               | 
               | The main challenge in a decarbonized energy sector
               | (including heat!) is not week to week or day to day
               | variability but season to season. That's best solved with
               | power 2 gas and storage whether the major source of
               | energy is nuclear (leaving nuclear reactors on idle for
               | half the year is expensive) or renewables.
        
               | 08-15 wrote:
               | Germany has the most expensive electricity in the world
               | (excluding Diesel powered islands). Electricity in
               | neighboring France is a third or so of the price. Is that
               | because France gets so much more sunlight?
        
               | Certhas wrote:
               | Besides what the sibling pointed out: choices and
               | subsidies, determine consumer prices. Coal subsidies
               | still are vastly larger than renewable subsidies world
               | wide. Compare the price of new wind and new nuclear
               | stations.
               | 
               | That admittedly doesn't give you total system cost, but
               | you need solid models for that anyways, as
               | electrification of mobility and heating will completely
               | change demand structure in the electricity secto.
               | 
               | The consumer price of electricity in Germany and France
               | tells you absolutely nothing about any of that.
        
               | aurelwu wrote:
               | That's vastly inaccurate. It is correct for household
               | prices, but for energy intensive industry the difference
               | is much smaller, something around 2 cents.
        
       | Pfhreak wrote:
       | I've been learning about biochar/syngas production from biomass.
       | 
       | It turns out there's methods that range from 'burn slash in a
       | giant metal bucket' to large industrial gassifiers for producing
       | biochar.
       | 
       | There's a part of me that wants to exit the tech sector, buy a
       | couple hundred acres nearby, live modestly, and tinker with
       | biochar production/sequestration.
        
         | SuoDuanDao wrote:
         | I met a guy who made biochar on the woodlot of someone he had
         | an arrangement with - woodlot owners are always looking for new
         | ways to monetise their lots, you may be able to tinker with
         | biochar production/sequestration without the big upfront
         | investment, this guy did it with a few weekends (and free
         | labour from people who wanted to learn the technique) a year.
        
         | swiley wrote:
         | Drying plants in the sun is a surprisingly effective way to
         | heat a building, I grew up with it.
         | 
         | The problems are: burning wet stuff is terrible (surface
         | wetness isn't bad, it's the moisture inside the biomass that
         | causes problems.) Secondly you can't just straight up burn it
         | because you'll get a lot of heat that you don't need so you'll
         | usually burn it in cycles and you'll get a lot of soot at the
         | beginning and end of the cycles so you need to either wash the
         | exhaust or make sure you don't have nearby neighbors downwind
         | (in places like this that means within a quarter mile or so.)
        
           | Pfhreak wrote:
           | For sure, excess heat is something that is interesting to
           | explore.
           | 
           | Oregon Kilns are basically just a big metal bucket that burns
           | top down and produces biochar, but burns off the syngas.
           | 
           | https://www.nrcs.usda.gov/wps/portal/nrcs/detail/or/newsroom.
           | ..
           | 
           | Other systems try to capture the syngas/bio oil to generate
           | electricity or capture the heat for heating/other uses.
        
       | jabl wrote:
       | This seems like a nice improvement for processing biomass waste
       | 
       | - less of the input energy wasted compared to traditional
       | charcoal production.
       | 
       | - retains coal advantages compared to less processed biomass,
       | namely higher heating value meaning cheaper to transport, and
       | easier to store (doesn't rot if it sits in a pile outside)
       | 
       | However, as a side note I'm very sceptical wrt bioenergy. Using
       | biomass waste for energy is fine if there's no other use for it,
       | but growing biomass for energy production really isn't. Next to
       | climate breakdown, the most serious ecological problem we're
       | facing is biodiversity loss, largely due to conversion of
       | wilderness to farmland. We really need to get past the idea that
       | every hectare of land has to be put to "productive" use. Much
       | better to produce our energy with wind, solar, hydro, geothermal,
       | and nuclear, and rewild nature to the extent possible.
        
       | swiley wrote:
       | It's important to note that (although I only skimmed it and am
       | not a professional chemist) they only talk about hydrocarbons up
       | to 6 carbons long (hexane) where coal/coke from the ground can
       | have much longer hydrocarbons (what paraffin wax is made of.)
       | This is because the hexane comes (probably) from sugar molecules
       | (or monomers in things like cellulose) which are chains or rings
       | of six carbon atoms (with other stuff bonded to them.)
       | 
       | It's possible to lengthen the hydrocarbon chains but it's very
       | expensive.
       | 
       | EDIT: yeah after reading more carefully they're doing what I
       | thought (side note: the dick bar was pretty annoying, at least it
       | goes away when you scroll down but coming back when scroll up and
       | covering the text I was trying to read is just dumb.) They're
       | drying/dehydrating the biomass by heating it without oxygen and
       | then distilling off the VOCs. Then they take the remaining gunk,
       | crush it up, sift it, and dry it.
        
       | hootbootscoot wrote:
       | climate crisis, hello... fossil fuels are a dangerous anachronism
       | to be gotten over, hello...
       | 
       | (renewable or not, net carbon emitter and HOW...)
        
       | agumonkey wrote:
       | while we're on cellulose, anyone heard of homelab-scale methods
       | to produce cellulasic enzymes ?
        
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       (page generated 2020-01-05 23:00 UTC)