[HN Gopher] Lasers etch a 'perfect' solar energy absorber
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       Lasers etch a 'perfect' solar energy absorber
        
       Author : clouddrover
       Score  : 126 points
       Date   : 2020-02-06 10:29 UTC (12 hours ago)
        
 (HTM) web link (www.rochester.edu)
 (TXT) w3m dump (www.rochester.edu)
        
       | logfromblammo wrote:
       | > _"...etching a full-color photograph of a family into the
       | refrigerator door; or proposing with a gold engagement ring that
       | matches the color of your fiancee's blue eyes. "_
       | 
       | Yeah... they should have stopped at car colors.
        
       | vorpalhex wrote:
       | Can we get a title update? Article reads `Lasers etch a 'perfect'
       | solar energy absorber`.
        
       | adrianN wrote:
       | This is of course a neat tech demo, but I don't really see the
       | application. Thermal electrical generation seems to be crap
       | compared to photovoltaics and for just heating stuff up, black
       | paint must be orders of magnitude cheaper, even if it might not
       | be a "perfect" absorber of sunlight.
        
         | mrfusion wrote:
         | If it could work on plastic this would be amazing for rooftop
         | pool solar heaters.
        
           | Gravityloss wrote:
           | In mediterranean countries hot water is regularly heated with
           | rooftop tanks / heaters. This could mean higher temperatures
           | achieved with that relatively easily.
        
         | logfromblammo wrote:
         | Materials that are perfectly black in visible and near-infrared
         | light, and mirrors in thermal infrared would be naturally warm.
         | Materials that are mirrors in visible light and perfectly black
         | in far infrared would be naturally cool.
         | 
         | If you paired those materials, you could collect solar energy
         | on the hot end, and radiate thermal energy into empty space on
         | the cool end, and put a Stirling engine between them. Then you
         | have a heat engine that does not dump its waste heat into the
         | atmosphere. At the theoretical limit, that means your
         | passively-radiating cool end can approach 3 K, instead of 300
         | K.
         | 
         | So you take a huge polished stainless steel dome, and etch the
         | outside to be black at visible and near-infrared wavelengths,
         | from 200 nm to 8000 nm, and you take some smaller domes, etch
         | them to be black between 8000 nm and 14000 nm, and put them at
         | the focal points of some parabolic reflectors, all in the
         | shadow of the first dome, aimed at empty space. (8000 nm to
         | 14000 nm is the "infrared window", where the atmosphere is
         | mostly transparent to those wavelengths.)
        
           | BlueTemplar wrote:
           | Yeah they should team up with the guys that made the "anti-
           | solar panel" :
           | 
           | https://www.sciencenews.org/article/device-harnesses-cold-
           | ni...
           | 
           | (They just painted aluminium black...)
           | 
           | ----
           | 
           | EDIT: No, wait, that's a different team that the one I had in
           | mind ? I seem to remember them using a complex material that
           | _specifically_ took advantage of this  "infrared window" ??
           | 
           | ----
           | 
           | EDIT2 : Ok, same guy(s), slightly different device :
           | 
           | https://www.asme.org/topics-resources/content/new-solar-
           | ener...
           | 
           | > A thin wafer of germanium had the right properties: It is
           | fairly opaque at visible wavelengths, absorbing most incoming
           | sunlight, while being generally transparent at the mid-
           | infrared.
           | 
           | > Because most of the energy in the solar spectrum is in the
           | visible and near-IR range, Fan said, germanium could capture
           | solar energy for use in thermal or photovoltaic applications,
           | while allowing mid-IR energy to escape for radiative cooling.
           | 
           | > The Stanford team tested the concept with an experimental
           | device that placed a germanium wafer in front of a mid-
           | infrared emitter.
           | 
           | > As reported in a recent paper in the journal Joule, the
           | wafer absorbed enough sunlight to warm up by 24 degrees
           | Celsius, while the emitter sent enough radiation through the
           | infrared "window" to cool itself by 29 degrees Celsius below
           | ambient temperature.
        
             | logfromblammo wrote:
             | That's what I was thinking of. They laminated a reflective
             | material under a thin sheet that had a particular
             | absorption spectrum, with a thermally conductive bond, and
             | put fused silica on top of it to protect against weather.
             | 
             | Laser-etching of normally reflective metals makes the
             | material less complex. For one, you don't have to match
             | thermal expansion coefficients any more.
             | 
             | The night-sky radiative cooling concept is thousands of
             | years old-- https://en.wikipedia.org/wiki/Yakhchal --but we
             | have better materials now. India and Persia made ice by
             | filling shallow trays with water, insulating them
             | underneath with straw, and exposing the water to a calm,
             | clear, night sky.
        
         | VBprogrammer wrote:
         | I guess concentrating solar collectors might be a useful
         | application?
        
           | wiggler00m wrote:
           | Various potential applications in biomedical, environmental,
           | and energy fields.[1] Could improve the efficiency of solar
           | thermal power stations:
           | 
           | "Control over the absorption spectral range of surfaces is of
           | major importance for a wide range of applications, such as
           | selective solar absorbers, thermal emitters, structural
           | colouring water condensation and daytime and night-time
           | radiative cooling. In particular, for a solar-thermal energy
           | absorber operating at high temperature, the absorber should
           | be an SSA since the main cooling mechanism is thermal
           | radiation... an ideal solar light absorber has nearly 100%
           | absorbance within the solar spectrum and negligible thermal
           | emittance within the blackbody radiation spectral range at
           | mid-to-high temperatures (100-500 degC), i.e., an SSA. SSAs
           | can thus maximise the temperature of solar absorbers and
           | increase the efficiency of a heat engine driven by solar
           | radiation."
           | 
           | [1] https://www.nature.com/articles/s41377-020-0242-y (full
           | text paper)
        
           | jvanderbot wrote:
           | Yes, any application requiring direct heat avoids electric
           | heater losses. Alternatively, using this to generate
           | electricity runs up against thermal electric losses.
        
           | mikro2nd wrote:
           | I'd hazard that this would be an obvious "first application"
           | for this technique. If they can improve the absorption
           | efficiency by 130%, that translates to reducing the number of
           | mirrors by something like 25%, so a fairly significant cost
           | saving. Alternately, if you can capture and store that energy
           | without increasing costs too much you end up with a more
           | efficient power plant per unit-area of land. Sounds good to
           | me!
        
         | jacobush wrote:
         | Sometimes you want the higher temperature, like in a kiln?
        
           | adrianN wrote:
           | Ah yes, that might be something. Tungsten might even retain
           | those nanostructures at higher temperatures. Good point.
        
         | jiofih wrote:
         | I was ready to debunk your comment, but then remembered that
         | existing solar thermal panels are at ~90% efficient already. Is
         | it somehow easier / more efficient to build a thermoelectric
         | generator from a metal, vs existing flat-plate + liquid
         | collectors?
        
           | mnw21cam wrote:
           | Solar thermal panels might be wonderful for heating up water
           | or buildings, where the target temperature is fairly low.
           | However, as the target temperature goes up, the target starts
           | radiating that heat energy back out, which is where this
           | innovation could be useful.
           | 
           | So, it's useful for applications where you want a higher
           | temperature than most solar heating applications now.
        
             | mrfusion wrote:
             | T^4 right?
        
       | ww520 wrote:
       | This sounds like magic. Very exciting. Is there a diagram or
       | video showing what the geometry looks like?
        
       | pjc50 wrote:
       | So the interesting thing is
       | 
       | > reduces heat dissipation at other wavelengths
       | 
       | Most of the time we use the "blackbody" approximation; and we're
       | familiar with the idea that black objects radiate and absorb heat
       | well, while white or shiny ones do not. This lets us make
       | something that absorbs like a black object and emits like a white
       | one. In effect its own surface is like a tiny greenhouse effect.
        
         | logfromblammo wrote:
         | Or absorbs at visible light frequencies and reflects at lower
         | thermal infrared frequencies.
         | 
         | Until the object starts to glow red-hot, it will have low
         | radiative losses. Once it gets that hot--maybe 3000K--it will
         | radiate very well, until cooling enough to radiate mostly at
         | the longer reflective wavelengths.
        
       | wiggler00m wrote:
       | Various potential applications in biomedical, environmental, and
       | energy fields.[1]
       | 
       | Could improve the efficiency of solar thermal power stations:
       | 
       |  _" Control over the absorption spectral range of surfaces is of
       | major importance for a wide range of applications, such as
       | selective solar absorbers, thermal emitters, structural colouring
       | water condensation and daytime and night-time radiative cooling.
       | In particular, for a solar-thermal energy absorber operating at
       | high temperature, the absorber should be an SSA since the main
       | cooling mechanism is thermal radiation... an ideal solar light
       | absorber has nearly 100% absorbance within the solar spectrum and
       | negligible thermal emittance within the blackbody radiation
       | spectral range at mid-to-high temperatures (100-500 degC), i.e.,
       | an SSA. SSAs can thus maximise the temperature of solar absorbers
       | and increase the efficiency of a heat engine driven by solar
       | radiation."_
       | 
       | [1] https://www.nature.com/articles/s41377-020-0242-y (full text
       | paper)
        
       | griffman99h wrote:
       | The Article also talks about hydrophilic and hydrophobic patterns
       | using the same setup. I would be interested in seeing the
       | properties of a channel or via through the tungsten etched with
       | these patterns. It might change the thermal absorption rate of
       | water passing through the hole or some other neat behavior like a
       | change to the capillary effect. This could improve concentrated
       | solar applications even further.
        
         | BlueTemplar wrote:
         | Just like the jellycat turbines ?
         | 
         | https://www.youtube.com/watch?v=mB5nztzXo24
        
       | icedistilled wrote:
       | Or maybe they catch use the tech to launch a competitor to the
       | holographic chocolate. http://www.morphotonix.com/chocolate/
       | 
       | Edit: Oh sad day, it seems the chocolate may have just been a
       | demo of the etching and molding technology.
        
         | BlueTemplar wrote:
         | :'(
        
       | scotty79 wrote:
       | > This improved the efficiency of thermal electrical generation
       | by 130 percent compared to untreated tungsten.
       | 
       | I wish they would include comparison to tungsten painted black.
        
         | jandrese wrote:
         | Maybe this is for applications where paint would be baked off
         | by the intense concentrated thermal radiation?
        
         | jerf wrote:
         | Embedded video says "15% more than previous black metal
         | samples", though that's still a bit non-specific.
        
       | mark-r wrote:
       | Is there any way to create a paint with the same properties,
       | absorbing visible wavelengths but reflecting infrared?
        
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       (page generated 2020-02-06 23:00 UTC)