[HN Gopher] Great AA Alkaline Battery Test (2016)
       ___________________________________________________________________
        
       Great AA Alkaline Battery Test (2016)
        
       Author : ValentineC
       Score  : 137 points
       Date   : 2022-01-12 18:15 UTC (4 hours ago)
        
 (HTM) web link (goughlui.com)
 (TXT) w3m dump (goughlui.com)
        
       | bentcorner wrote:
       | > _This can be implemented basically with a fixed value of
       | resistance, but because of the way resistance interacts with
       | voltage, it's actually very gentle on the battery. As the battery
       | voltage falls, the current falls accordingly, so the delivered
       | power falls even further. For modern appliances, this type of
       | loading is not common._
       | 
       | Dumb question - is it at all possible to design a modern device
       | which operates this way? (As battery voltage falls, device
       | performance also falls? It's been a really really long time since
       | my EE classes - are transistors just unable to operate this way?)
        
         | gruez wrote:
         | > It's been a really really long time since my EE classes - are
         | transistors just unable to operate this way?)
         | 
         | Yeah, most CPUs nowadays have dynamic frequency adjustment to
         | maximize battery life. Lower frequencies also mean transistors
         | can operate at lower voltages, so by reducing the operating
         | frequency, you can reduce the voltage and therefore power draw
         | on your battery.
        
         | sbierwagen wrote:
         | Some LED flashlights with multiple brightness modes will drop
         | to low brightness mode when cell voltage falls below a certain
         | point.
        
         | orev wrote:
         | Apple did this with iPhones, where the CPU throttles itself
         | when the battery can't keep up with the peak demand anymore.
         | They got sued for it (mostly because they didn't tell anyone
         | and people bought new phones when the old ones started
         | mysteriously slowing down).
        
         | dragontamer wrote:
         | Have you ever used an old flashlight in the 80s or 90s?
         | 
         | As AA charge fell, the light got dimmer and dimmer. Today, we
         | have devices that do the exact _OPPOSITE_, pulling the last
         | bits of electricity out of the cells through boost-converters
         | or whatnot (boost converters existed back then, but weren't as
         | efficient or cheap as today).
         | 
         | Consumers demanded consistent and reliable performance no
         | matter if at full-battery charge or nearly empty. People
         | preferred their devices to suddenly "shut off".
        
       | silisili wrote:
       | On the subject of AA alkaline batteries - one thing I learned a
       | long time ago somehow I'll share that people seem amazed by is
       | that you can approximate their charge by bouncing them on a hard
       | surface. Drop an AA battery negative/flat side down an inch or
       | two onto a hard surface like a counter or table. A new battery
       | will just land and thud. A dead battery will bounce
       | repeatedly(you'll hear it more than see it).
        
         | iancmceachern wrote:
         | I wonder what phenomenon is driving this. A spent battery
         | weighs more?
        
           | dragontamer wrote:
           | The physical chemistry changes as a battery is spent. The
           | internal chemicals are being converted from one molecule into
           | another.
           | 
           | Its not surprising to me that the two different chemicals
           | have different physical properties. (Elasticity, density, who
           | knows? They're a fully different chemical once the electrons
           | move around)
        
             | ChrisLomont wrote:
             | Almost all the mass of a molecule is in atom nuclei, and
             | these masses do not change under any battery chemistry I've
             | ever seen.
             | 
             | The only way to change mass appreciably is to add or remove
             | atoms from the interior of the battery.
        
           | exhilaration wrote:
           | Previously discussed on HN:
           | https://news.ycombinator.com/item?id=21693423
        
           | ztakeo wrote:
           | Here's a good reference https://pubs.rsc.org/en/content/artic
           | lelanding/2015/ta/c5ta0...
        
           | thescriptkiddie wrote:
           | IIRC alkaline batteries produce some kind of gas while being
           | discharged. When the battery is dead it is probably inflated
           | like an unopened soda can, assuming it hasn't leaked.
        
             | jandrese wrote:
             | Isn't that what the vents holes are for?
        
           | icodestuff wrote:
           | IIRC, new batteries contain a semi-liquid electrolyte, which
           | damps the bounce. When discharged, it becomes much more
           | rigid, so the battery bounces. Compare dropping a gallon jug
           | with ~a cup of water in it vs a cup frozen into ice to see
           | what i mean.
        
         | rytis wrote:
         | I didn't know that, thanks for sharing! It seems to be a lot
         | more civilised version of what I was doing for years - test by
         | licking it... Can do it almost in one gesture: hold the battery
         | between thumb and middle finger, lick index finger and touch it
         | on one end of the battery, then lick the other. With some
         | practice can get pretty good accuracy in 0.5-1.5V range. Bit
         | barbaric though :)
        
       | zh3 wrote:
       | Let me leap in here to ding Duracell. They used to be my goto
       | battery, but over the past few years (there was a hedge fund
       | takeover, which IME rarely results in improvements to long-
       | standing quality products) they've turned into liabilities -
       | specifically, they are extremely prone to leaking once even a
       | little bit discharged. To this day I open old kit and there can
       | be duracells in there with "use by 2010" or even earlier dates
       | which are fine, yet far newer batteries (e.g. bought in 2016 with
       | expiries in 2022) leak like there's no tomorrow for the buyout
       | team.
       | 
       | Interested to hear of others experiences, or I've just been
       | amazingly unlucky.
        
         | jasode wrote:
         | I came across this recent youtube comment[1] on why older
         | batteries didn't leak. I don't know if it's correct but sharing
         | it anyway:
         | 
         |  _> ceptimus 2 weeks ago (edited) >> Old alkaline batteries
         | contained mercury, which made them resistant to leaking. The
         | mercury was there to absorb the hydrogen gas, which builds
         | internal pressure when the battery is used, causing them to
         | leak. Newer alkaline batteries don't have mercury, because it's
         | harmful to the environment when disposed. Unfortunately, the
         | mercury free batteries leak much sooner - many of them long
         | before their 'use by' date, even if you've never used them. Now
         | you've replaced the batteries, you should check the camera more
         | frequently. The modern rechargeable Ni-mh batteries, with a low
         | self-discharge rate, are a good alternative: less likely to
         | leak; but they're only nominally 1.2 Volts per cell instead of
         | 1.5 volts, so some equipment won't work with them._
         | 
         | EDIT... maybe there's more to it than just mercury because some
         | low-effort googling[2] found that law prohibiting it in
         | batteries was 1996 (~25 years ago). That doesn't match the
         | timeline in the video because Alec says his old batteries (that
         | didn't leak) were "use-by-date-2016". So maybe something else
         | was different about the formulation in his Kirkland Signature
         | batteries circa ~2008.
         | 
         | [1]
         | https://www.youtube.com/watch?v=m5s6xerRqVY&lc=UgztQzUKV5BJQ...
         | 
         | [2]
         | https://www.google.com/search?q=mercury+removed+from+alkalin...
        
         | dv_dt wrote:
         | After using Duracell for years for applications where I had to
         | use alkaline, I recently had a set die with major leaks early,
         | basically ruining a nice LED flashlight.
        
         | Spooky23 wrote:
         | They are expensive, but if you _need_ a primary battery, the
         | non-rechargeable lithium batteries are great.
         | 
         | My clock radio backup battery has probably been in there for
         | >15 years.
        
         | pomian wrote:
         | That possibly explains the mysterious leaking battery problems.
         | I remember that was an issue over twenty five years ago, which
         | taught us not to leave batteries in devices. But then we
         | accepted that they don't leak anymore. Then in the last five
         | years or so, I keep finding gadgets that are destroyed, or
         | almost so, from massive battery leaks. And alkalines don't seem
         | to last very long, even though they are more expensive than
         | they were.
        
         | bxparks wrote:
         | Yup, I hate Duracell batteries with a passion, they leak like a
         | wet sponge and destroy electronics. I have converted most of my
         | batteries to NiMH, but for the few that cannot be
         | rechargeables, I will go out of the way to buy anything but
         | Duracells.
        
         | cjbgkagh wrote:
         | Happened to me. Duracell was my goto and now they leak. I don't
         | know who to trust anymore. Thankfully I'm not a big battery
         | consumer.
        
           | klodolph wrote:
           | As the article states, NiMH has gotten a lot better, and I
           | now use that nearly everywhere instead of alkaline.
           | 
           | It's nice not having to shop for batteries as often. I
           | plugged in a charger behind the TV and batteries in a drawer
           | under the TV. With the price point for Eneloop and Duracell
           | batteries, you break even once you use a rechargeable for the
           | fourth time.
           | 
           | Part of the reason I have it in the first place is that the
           | Roku 4's abysmal remote control goes through a set of
           | batteries once every three months or so.
        
             | tkojames wrote:
             | Rumor is the Ikea batteries are rebranded Eneloop I have
             | good luck with them.
        
               | bxparks wrote:
               | This website says that the IKEA brands are equivalent to
               | the Eneloop Pro and Lite, but not the regular white ones:
               | 
               | https://eneloop101.com/batteries/rewrapped-batteries/
               | 
               | (Scroll/search to "IKEA")
        
               | tecleandor wrote:
               | Seems like at least the AA size, model LADDA 2450mAh. You
               | can check they're made in Japan. Not sure about the 1900
               | mAh, or the AAA size model, it might be a different
               | brand.
        
               | jq-r wrote:
               | I have a lot of those white ones, and they work great for
               | years now. They're a steal.
        
           | Wistar wrote:
           | Anyone know who makes the Costco Kirkland brand AAs?
        
             | Moru wrote:
             | Producer likely to change depending on who does them
             | cheapest at the time.
        
               | Scoundreller wrote:
               | And sometimes varies by region.
        
         | justjash wrote:
         | Same. I pulled down my dad's old camera from the closet a few
         | years ago and it probably hadn't been used since the 90s so the
         | batteries were dead. Threw in some new Duracell batteries and
         | played with it a bit before putting it away. Opened it a year
         | or two later and the batteries had swelled and leaked
         | everywhere. Had to use a pair of pliers to extract the swollen
         | batteries from the battery compartment. Such a huge pain.
        
         | jacobolus wrote:
         | Duracell (the Mallory company) was bought by Dart in 1978, then
         | by KKR in 1988, Gillette in 1996, Procter & Gamble bought
         | Gillette in 2005, and Duracell was spun off and bought by
         | Berkshire Hathaway in 2016. (source: Wikipedia)
         | 
         | The company has been under large-scale finance / conglomerate
         | management for more than 4 decades by now. I don't think there
         | would have been any immediate change in battery quality circa
         | 2016. Seems just as likely that corner cutting (assuming there
         | is corner cutting; I have no insight) started before changes of
         | ownership.
        
         | JTbane wrote:
         | Yep, have the same experience here. Even worse, I have devices
         | which require batteries to be installed for memory retention,
         | so I can't really remove all the alkalines to prevent leakage.
        
         | jolux wrote:
         | It wasn't a hedge fund, it was Berkshire Hathaway.
        
         | ASalazarMX wrote:
         | Happened for me too. They were very reliable batteries, now
         | even new batteries leak if unused for a few years. They have
         | ruined several remotes that I use sparingly, they should change
         | their name to Ephemeralcell.
        
         | Isthatablackgsd wrote:
         | Mmm, I recalled I had Duracell (bought in 2018, expire date
         | 2025) leaked in the battery compartment and I don't use the
         | device. I just assumed the device was on standby mode and been
         | draining the battery for a while which caused the leaking.
         | 
         | That mean I have to be wary of Kirkland AA and AAA Batteries
         | because they are made by Duracell. This is new for me and I'm
         | surprised about Duracell, and I am not surprised about hedge
         | fund/private equity. This is their MO.
        
           | siegecraft wrote:
           | Kirkland batteries were very leaky to the point where I
           | didn't even finish using the pack I bought. I was quite
           | dismayed since Kirkland usually has quality products.
        
         | CWuestefeld wrote:
         | More anecdata - I don't have anything to add regarding
         | Duracell, but I've experienced the same thing you describe with
         | Energizer.
         | 
         | Recently I've leaned toward ACDelco batteries, which aren't on
         | the test list.
        
           | wlesieutre wrote:
           | I had no idea ACDelco made anything other than car parts,
           | huh.
        
         | gunapologist99 wrote:
         | Curious if you're having these leaks in Duracells you bought
         | from a big box retail store, or shipped from Amazon.
        
           | gerdesj wrote:
           | You mean ... _gasp_ ... they might be fakes.
           | 
           | The EU has a quality mark "CE" - Conformite Europeenne.
           | Sometime the font is a bit wonky and it is alleged that CE in
           | that case stands for China Export instead. I imagine that
           | https://en.wikipedia.org/wiki/CE_marking#%22China_Export%22
           | is policed quite carefully.
        
           | brnt wrote:
           | I get Duracell Industrials through my works office supplier,
           | they also leak frequently.
        
         | grumpyprole wrote:
         | Completely agree. Duracell batteries have been leaking
         | consistently for me, I've stopped buying them and actively warn
         | others. They have destroyed various remotes, torches and an
         | expensive camera flash after only a few years.
        
         | jhallenworld wrote:
         | But I think their NIMH batteries are good. Project Farm
         | reviewed them, they were near the top. Of course I'm looking
         | for good ones that are cheaper..
        
         | TrainedMonkey wrote:
         | Anecdata, I recently had to replace batteries in several smoke
         | alarms. 3 were Duracells and 2 were Rayovacs. All Duracells
         | were from 2016/2017, i.e. assuming they were installed right
         | away they lasted around 5 years. Rayovacs were from 2010 and
         | 2011, despite both brands being rated for 5 years. It is
         | possible that old Rayovacs were installed around same time as
         | new Duracells and both lasted around same time, still makes for
         | an interesting datapoint.
        
           | bluGill wrote:
           | Rayovac was bought out by Energizer not too long ago. They
           | used to have a 10 year no leak guarantee, now they leak in a
           | few months as I've learned the hard way.
        
           | adenner wrote:
           | Just as a bit of feedback, for safety equipment like smoke
           | and CO detectors, standard guidance is to replace the battery
           | at least once a year. (Unless you have an integrated 10 year
           | battery that will last the life of the detector)
           | 
           | If you live in an area that follows Daylight Savings time,
           | doing it then is best so that you remember. Otherwise doing
           | it during the Operation Edith drill for Fire Prevention Week
           | is the next best.
        
             | TrainedMonkey wrote:
             | Does this guidance apply to both battery backup and battery
             | only situations?
        
         | surge wrote:
         | Someone did a test and found the Costco Kirkland batteries were
         | not only as good as Duracell, but cheaper and lasted longer.
        
         | tablespoon wrote:
         | > there was a hedge fund takeover, which IME rarely results in
         | improvements to long-standing quality products
         | 
         | But think of the shareholder value that was created!
         | 
         | https://web.archive.org/web/20121120072539/https://www.newyo...
        
         | bwbmr wrote:
         | Same here, lots of leaks-- some family even has had a drawer
         | full of unexpired Duracells leak. Myself, I've switched over
         | completely to NiMh except when unsupported by the device to
         | remove the change of leaks (Nest x Yale door lock in
         | particular, which detected NiMh as low battery even when 90% of
         | the cell capacity is remaining). AmazonBasics has been bad with
         | leaks too.
         | 
         | Edit: I have a Powerex MH-C980 and that has significantly made
         | using NiMh easier. Before with a bundled Panasonic charger I
         | had to charge everything in pairs, 4 max. The Powerex I can
         | charge 8 cells individually, turbo charge if I'm in a rush, and
         | see how much energy actually was used if something seems to be
         | eating through a lot of batteries.
        
           | Moru wrote:
           | Just to clarify your point there: Charging batteries as pairs
           | is what kills the rechargeable batteries. There is no way for
           | the charger to keep track of both batteries at the same time
           | so it just charges until both should be done.
           | 
           | If one of them is bad, the charger will kill the other one
           | too. If they are differently charged, it will kill one of the
           | batteries and next time it will kill the other battery. (Kill
           | as in make worse and worse until it finaly doesn't charge at
           | all.)
           | 
           | I have mostly stopped using rechargeable AA and AAA batteries
           | because of the bad quality of the last ones I bought. They
           | took 3-5 charges before dying with a good charger that does
           | all batteries separately.
        
             | MaKey wrote:
             | Modern chargers are microprocessor controlled and are able
             | to keep track of each battery individually.
        
             | zackees wrote:
             | Also, NiMH batteries can reverse charge and ruin
             | themselves. This happens a lot when batteries are in series
             | and the load will continue to run the batteries until 0
             | voltage. The weakest battery will deplete first but then
             | the other batteries will continue to pump current through
             | until that weak battery reverses polarity and wrecks
             | itself.
        
       | reiichiroh wrote:
       | Anyone remember the rechargeable alkaline brand "Pure Energy"
       | available in Canada?
        
       | moreati wrote:
       | Note, this is from 2016.
        
         | CamperBob2 wrote:
         | Indeed, and one major change that's taken place in the last few
         | years is that Energizers are now as leak-prone as Duracells.
         | Likely true of other brands as well. The only way to win the
         | alkaline battery game is not to play.
        
       | colanderman wrote:
       | Re: constant current appliances, most any "digital" appliance
       | that uses a linear regulator (as opposed to a DC-DC converter)
       | will exhibit such a load profile.
        
       | zw123456 wrote:
       | This is really amazing work, I found part 3 to be the most
       | interesting https://goughlui.com/2016/12/19/great-aa-alkaline-
       | battery-te... particularly the mwh/$ and other charts like
       | capacity vs. weight etc.
        
       | zwieback wrote:
       | I know what I'll pick up next time I'm at IKEA.
        
       | wrjensen wrote:
       | I have had the same issues with Duracell leakage. I won't buy
       | them any more, for exactly that reason.
        
       | RicoElectrico wrote:
       | There's also http://lygte-info.dk/ which has a ton of battery and
       | charger tests. Definitely worth reading.
        
       | walrus01 wrote:
       | something that didn't exist in 2016 and does now, are AA
       | batteries that are composed of an internal lithium ion cell, a
       | DC-DC converter for 1.5VDC output to the end terminals, and
       | internal 5V-USB to li-ion charge controller circuitry.
       | 
       | With a USB port literally built into the body of the battery.
       | They're more expensive, but can pay for themselves...
       | 
       | https://www.amazon.com/AA-Batteries-ANVOW-Rechargeable-Capac...
       | 
       | there are lots of other models if you search for "AA battery
       | lithium ion USB"
       | 
       | I would recommend these over anything that is NiMH based (memory
       | effect) or needs a proprietary charger.
        
         | intrasight wrote:
         | I'd seen those in the past. Prices have come down. Am curious
         | what are the benefits over NiMN.
        
       | warpech wrote:
       | Also see this impressive test:
       | https://anrieff.net/batterytest/index_en.html (European market)
        
       | zoomablemind wrote:
       | Chiming in, I just recently was wondering how two seemingly equal
       | by chemistry and size batteries just from different mfgrs could
       | be so much incomparable by practical life-times.
       | 
       | On so many occasions Panasonic or Sony (Japan made) batteries
       | which come included with devices (like remote controls etc) would
       | last years (!) (in some odd case I had Sony AA battery functional
       | after more than a decade), yet any recent replacements from
       | Duracel or Energizer the ones bought from a pharmacy would get
       | exhausted within a year of similar use.
       | 
       | There must be some difference there, just how to tell what is
       | that?
        
       | LeoPanthera wrote:
       | There's very little reason to continue using Alkalines in the
       | majority of cases. Rechargeable batteries both last longer, and,
       | perhaps even more importantly, do not leak.
        
         | johndough wrote:
         | Rechargeable batteries (assuming NiMH and Ni-Cd) can still
         | leak, but usually the leakage is less severe.
        
       | Maarten88 wrote:
       | As a test I recently bought a pair of Li-ion AA batteries, that
       | are recharged through a micro USB connector in the battery. They
       | are rated 2880 mWh and are advertised to provide a flat 1.5v
       | during the whole discharge cycle (they have internal circuitry to
       | convert from the native 3.7v).
       | 
       | I wonder how those compare to my current rotating stock of Ni-MH
       | ones that regularly stop working. Jury is still out, they were
       | considerably more expensive though (something like EUR4.50 a
       | piece).
        
         | discreditable wrote:
         | I have some similar Li-ion AA batteries for my Blink cameras.
         | They work very well since the Blinks hate ni-mh batteries.
         | Interestingly, these behave oddly in my camera speedlite. They
         | can't seem to charge the flash, and the LCD flickers while on.
         | My best guess is the charging the flash capacitor pulls more
         | juice than the lithium batteries can handle. Thankfully, ni-mh
         | work great.
         | 
         | For your Ni-mh that stop working, if they won't charge you can
         | sort of jump start them using a good battery and they'll charge
         | again. Use some aluminum foil strips and touch the contacts
         | between the batteries together for a few seconds. Positive to
         | positive, negative to negative if I remember correctly.
        
       | wmorein wrote:
       | Apologies for the slightly off topic question but can anyone
       | point me to the best test/comparison of Alkaline batteries vs.
       | the new Lithium rechargeable ones? Older rechargeable AA and AAA
       | batteries were terribly short lived and so mostly useless but I
       | assume Lithium ones are much better?
        
         | dragontamer wrote:
         | > the new Lithium rechargeable ones
         | 
         | Lithium isn't rechargable. (Lithium AA cells are very long-life
         | but very expensive. One-time use. Lithium-ion are rechargable,
         | but are 3.7 volts and completely violate the AA spec)
         | 
         | NiMH is the chemistry for rechargable AA / AAA cells, since its
         | 1.35V and "close enough" to the old 1.5V standard alkaline.
         | 
         | > Older rechargeable AA and AAA batteries were terribly short
         | lived and so mostly useless but I assume Lithium ones are much
         | better?
         | 
         | "Older", circa 00s NiMH chemistries had more energy storage
         | (!!!). The issue was that circa 00s cells had a "self-
         | discharge" problem, meaning they ran out of energy in just a
         | few months (like 1 to 3 months).
         | 
         | Panasonic solved the problem with "Low Self Discharge" cells,
         | aka "Eneloop", which started to come out in the late 00s. This
         | chemistry had much less capacity, but took over a year before
         | the energy went bad.
         | 
         | Its still NiMH chemistry, but just tweaked to focus on the
         | self-discharge problem rather than energy-storage numbers /
         | benchmarks.
         | 
         | With Eneloop taking the market by storm (especially popular
         | with XBox users, which used AA rechargables), other companies
         | also came out with LSD chemistries. These days, almost
         | everything you'll find is of the LSD-type.
        
           | rabf wrote:
           | You can get lithium ion rechargable AA batteries these days.
           | They have a built in regulator to drop the voltage to 1.5V.
           | Some of them even have micro usb ports on the side for
           | charging.
        
             | walrus01 wrote:
             | there are even USB-C ones now for people who have less
             | microUSB 5VDC charge cables hanging around their home...
        
           | wmorein wrote:
           | Ah, I totally misunderstood the current state of thing. But
           | happy I asked -- thanks for all the info.
        
         | Zak wrote:
         | Here's one: https://lygte-
         | info.dk/review/batteries2012/CommonAAIndividua...
         | 
         | Note the small link near the top titled "Comparator" if you
         | want to generate comparison graphs between different batteries.
         | 
         | 1.5V Li-ion rechargeable AAs are 3.7V cells with DC-DC buck
         | converters attached to reduce the voltage. The main reason to
         | use them is poorly-designed[0] devices that don't play well
         | with NiMH. There may be some standby power drain from the
         | electronics, and these are less compatible with voltage-based
         | battery status monitoring than NiMH (NiMH gives a false low
         | reading; bucked Li-ion gives a constant false full reading).
         | 
         | Modern low-self-discharge NiMH has very good performance and
         | shelf-life; the white Panasonic Eneloop is the gold standard in
         | this category; the black ones have higher capacity, but wear
         | out in fewer charge cycles.
         | 
         | [0] Even if designing for alkaline without NiMH support isn't a
         | design flaw per se, a device that doesn't work at 1.2V leaves
         | about half the energy stored in an alkaline unused.
        
         | tzs wrote:
         | I've been a bit puzzled by the 1.5 V lithium AA batteries I see
         | on Amazon. They say they are a constant 1.5 V all the way from
         | 100% charged to 0% charged.
         | 
         | With the battery presenting a constant voltage, wouldn't that
         | make battery level displays useless? They rely on the voltage
         | declining as the battery discharges. With a constant 1.5 V
         | battery your device is going to say the battery is full right
         | up until it suddenly stops.
         | 
         | I'd expect that to get very annoying.
         | 
         | Edit: I mean the 1.5 V lithium rechargeable AA batteries, like
         | these: https://www.amazon.com/Deleepow-Rechargeable-Lithium-
         | Batteri...
        
           | grumbel wrote:
           | The AA lithium-ion rechargeable are internally 3.7V, just
           | like any other lithium-ion battery. They have a buck
           | converter build-in that regulates that down to a constant
           | 1.5V. Which can be handy in the handful of applications that
           | don't deal with the 1.2V that NiMH provide. This does in turn
           | make battery indicators indeed completely useless for many of
           | them, as there is no detectable drop in voltage from the
           | outside of the battery.
           | 
           | However, there are newer ones take care of that and regulate
           | the voltage down to 1.1V or so shortly before they run
           | completely out of juice, so that the battery indicator can
           | give a warning. Don't know how widespread that feature is
           | yet, but it exists.
        
           | dragontamer wrote:
           | When in doubt, https://data.energizer.com/
           | 
           | For Lithium chemistry:
           | https://data.energizer.com/pdfs/l91.pdf
           | 
           | That's Energizer's Lithium of course, but you can expect that
           | competitors probably perform "similarly".
           | 
           | ------
           | 
           | You can see that Energizer Lithium is 1.7V, slightly more
           | than the 1.5V found in typical Alkaline cells. Today's
           | electronics are pretty flexible however, and this may not be
           | an issue. (In practice, AA-devices are usually designed for
           | 1.35V NiMH, 1.5V Alkaline, and 1.7V... but there are some
           | devices that have made 1.5V assumptions and _ONLY_ work with
           | Alkaline)
        
             | tzs wrote:
             | Oops. I meant 1.5 V rechargeable lithium AA batteries, but
             | left out "rechargeable". I've edited my comment to fix
             | this.
             | 
             | The 1.5 V rechargeable lithium batteries couple a
             | rechargeable lithium cell with a buck converter to drop the
             | voltage to 1.5 V.
             | 
             | I haven't seen any that are sophisticated enough to use a
             | variable output buck converter and drop the voltage as the
             | underlying battery discharges.
        
         | bradfa wrote:
         | I've not seen AA or AAA sized lithium rechargeable batteries
         | but modern low-self-discharge NiMH AA and AAA cell batteries
         | are quite good today. The Panasonic Eneloop brand are generally
         | widely available and good value for money. The AA size Eneloops
         | are generally around 2100mAh and the AAA size around 900mAh.
         | 
         | The only downside to modern NiMH batteries today seems to be
         | finding a good and easy to use charger which will properly
         | discharge and/or cycle the batteries without requiring a human
         | to fiddle with it or understand charge rates and when to
         | discharge the cell prior to charging.
        
           | dragontamer wrote:
           | > The only downside to modern NiMH batteries today seems to
           | be finding a good and easy to use charger which will properly
           | discharge and/or cycle the batteries without requiring a
           | human to fiddle with it or understand charge rates and when
           | to discharge the cell prior to charging.
           | 
           | Only if you're really babying your NiMH cells is it
           | worthwhile to do this.
           | 
           | -----
           | 
           | Frankly, my recommendation is to just throw away NiMH cells
           | once they "go bad" (maybe a discharge/recharge cycle will
           | save them, but they're really not that expensive).
           | 
           | For most consumers out there, the $10 trickle charge that
           | takes 8+ hours is superior, because they'll never cycle the
           | NiMH cells to death. How many dozens of charge/recharge
           | cycles do you need before there's an issue, even with the
           | most primitive of charging strategies?
           | 
           | When it takes months for a typical AA powered appliance to
           | run out of NiMH charge, you realize that these "dozens" of
           | charge/discharge cycles gives a life-span measured in _YEARS_
           | for these NiMH cells.
           | 
           | After 5 years, your NiMH cells might be on its last legs,
           | needing a full discharge/recharge to get back to full power.
           | Then and only then should you consider a $30 charger to
           | perform this resurrection, except its probably more cost-
           | efficient to just spend $2 and throw away the "old" cell.
           | 
           | You'll need to throw away $20 worth of cells (ie: 10 cells)
           | before your $30 fancy charger with discharge/recharge cycles
           | + coulomb counting is superior to the $10 crap trickle
           | charger. Maybe an RC-car enthusiast will get there (or an
           | electronic-hobbyist), but that's a _LOT_ of charge/recharge
           | cycles before you reach this point. Even with the inferior
           | $10 trickle charge design.
           | 
           | -------
           | 
           | EDIT: That being said, spending $30, $40, or $50 on a higher-
           | end charger because you find it "cool" is probably
           | worthwhile. Coolness is a factor and we're not really talking
           | about a lot of money here. But the $10 charger + buy new
           | cells as needed approach is probably the most cost-effective
           | strategy.
        
           | jerlam wrote:
           | There are AA and AAA sized lithium ion rechargables, but they
           | won't work in anything that uses alkalines, since they
           | provide a very different voltage (3.7V). They are usually
           | called 10440 (AAA-sized) and 14500 (AA-sized).
           | 
           | There are AA and AAA lithium _primary_ batteries that provide
           | 1.5V and are in stores, but they cannot be recharged. They
           | are far superior than alkalines in most ways, especially in
           | the cold, but they cost drastically more, around $1-2 each.
           | I've switched many of my low-drain applications to these
           | batteries, where they are likely to outlast the device
           | without leaking and destroying it.
        
             | tzs wrote:
             | There are now 1.5 V lithium rechargeable AAs. Here's a
             | typical example [1], and there are a ton of others.
             | 
             | I am almost certain they are implemented as 3.7 V lithium
             | rechargeable batteries combined with a buck converter to
             | get the 1.5 V output.
             | 
             | I think they are relatively new. I don't recall noticing
             | them a few years ago, which was the last time I was looking
             | for rechargeable AA batteries.
             | 
             | [1] https://www.amazon.com/Deleepow-Rechargeable-Lithium-
             | Batteri...
        
       | rdl wrote:
       | Duracell used to be really good about replacing devices if their
       | batteries leaked. They screwed me a couple years ago and refused
       | to replace something (a $50 apple keyboard, I think they gave me
       | $10 for it?). I went from buying exclusively Duracell for
       | alkaline to now just buying Energizer Lithium for everything
       | where it isn't specifically contraindicated (very rare).
        
         | zh3 wrote:
         | Yes, I too have switched to Energizer - zero problems to date
         | (switched from Duracell some years ago).
        
       | Normille wrote:
       | Check out 'Project Farm' on YouTube for a couple more in-depth
       | tests of AA batteries
       | 
       | TLDR:
       | 
       | Made in Japan = GOOD Made in China = BAD
        
         | Isthatablackgsd wrote:
         | I love how he made it clear where it was assembled in. Every
         | time he said "Made in USA with Global Components!", I was like
         | yea more like made in China and rebranded in USA.
        
           | csdvrx wrote:
           | We need a new slogan: "rebranded in USA with a total lack of
           | pride"
        
       | CamperBob2 wrote:
       | Spoiler: they're all obsolete cost-reduced leaky pieces of shit.
       | Use Eneloops or other NiMH rechargeables when possible, lithium
       | primary cells otherwise.
       | 
       | For a while you could avoid leakage by steering clear of Duracell
       | in favor of Energizer, but that's no longer true. _Do not use
       | alkaline AAs or AAAs in any equipment you want to keep._
        
       | dragontamer wrote:
       | I think the main issue with AA Alkaline is the proliferation of
       | cheap low-self-discharge NiMH cells (aka: Eneloop, but also
       | Energizer and other brands have good LSD NiMH available).
       | 
       | A huge number of appliances seem to be designed for the 1.35V
       | NiMH chemistry now. Perhaps a random TV-remote still prefers
       | Alkaline but most seem to work fine with NiMH.
       | 
       | -----
       | 
       | Buying a pack of 20 NiMH cells and rotating your collection
       | between charging / discharging states is cheap enough and
       | effective. Its like you have "infinite" AAs since you can just
       | keep recharging them.
       | 
       | EDIT: A few years ago, Alkaline was still needed for TV remotes.
       | But most Low-self-discharge NiMH now lasts for over a year
       | without self-discharging away. Sure, not as good as Alkaline's
       | 10-year life span but surely 1+ year lifespans is good enough for
       | your TV remote? Its not that big of a hassle to reach recharge
       | your NiMH once a year is it?
        
         | djrogers wrote:
         | That works well until you have kids running around... You going
         | to put rechargeable cells in that Elena of Avalor wand your 4
         | year old chases the dog with? And her talking unicorn? How
         | about all the light sabers?
         | 
         | In my experience, most of those types of toys don't go through
         | batteries fast enough to justify a NiMH - they'd be in there
         | for years. Invariably one of the kids will wind up mixing
         | NiMH/LiIon/Alkaline in a toy, then the rechargeable winds up in
         | the recycling bin a year later.
         | 
         | Fast forward 3 years, and your "infinite" AAs are all gone,
         | lost, or in near-permanent use somewhere you can never
         | identify, and you've wasted all that money.
         | 
         | In a few years when the kids move out and, and the number of
         | battery powered gizmos is down to a manageable number, I'll try
         | it again - until then, Amazon Basics AAA/AA are my friend.
        
         | klodolph wrote:
         | > A huge number of appliances seem to be designed for the 1.35V
         | NiMH chemistry now.
         | 
         | Yes, this is my experience too. One of the problems with NiMH
         | is that appliances have helpful low-battery indicators which
         | might light up as soon as you put NiMH cells in them, even
         | though the appliance might continue working for a long time
         | yet. A prime example is the Nintendo Game Boy Advance, which
         | was released in 2001. The thing is powered by switching
         | regulators which work fine with the lower voltages of NiMH
         | cells!
         | 
         | Newer appliances have solved these problems. For example, the
         | Yamaha PSS-A50 (a fantastic, inexpensive portable keyboard) has
         | an option to configure the low-battery indicator for alkaline
         | or NiMH chemistry.
        
           | ace2358 wrote:
           | Totally agree! My Game Boy Advanced power light is green for
           | about an hour then red for hours and hours on my eneloops.
           | Also my Tascam field recorder has the option for alkaline or
           | NiMH batteries.
           | 
           | I still have some kitchen scales that won't work with NiMH
           | though :(
           | 
           | I've had my energiser batteries for almost 10 years and I've
           | been rotating them through devices and the charger. Only
           | recently have I begun to lose some cells.
           | 
           | Time to upgrade them all to eneloops!!
        
             | mikepurvis wrote:
             | A quick googling reveals nothing, but I wonder if a simple
             | hardware mod could address this-- basically, identify the
             | voltage divider that's doing the measurement across the
             | battery and change out one of the resistors so that it
             | "sees" 1.35V as 1.5V.
             | 
             | Most GBA battery mod posts are about people upgrading units
             | to have built-in lithium packs, USB-C charge ports, etc
             | etc.
        
               | dragontamer wrote:
               | Nope.
               | 
               | Alkaline at 100% charge is 1.5V, at 50% charge it's 1.2V,
               | at 0% charge it's .9V.
               | 
               | NiMH at 100% charge is 1.35V, at 50% charge it's 1.35V,
               | at 0% charge it's like 1.2V
               | 
               | Totally different discharge curves. There's no simple
               | circuit to convert between the two.
               | 
               | -----
               | 
               | EDIT: For hard data, see:
               | 
               | Energizer NiMH :
               | https://data.energizer.com/pdfs/nh15-2300gl1220.pdf
               | 
               | Energizer Alkaline:
               | https://data.energizer.com/pdfs/e91gl0320.pdf
        
               | mikepurvis wrote:
               | Oh yeah, I'm aware that for any other chemistry you need
               | an actual coulomb-counter to get a proper gas gauge. My
               | suggestion was more about the specific matter of
               | suppressing an unwanted and inaccurate low battery light.
               | 
               | Though maybe instead of trying to mod the circuit board,
               | it would be easier to just disconnect the LED itself.
        
             | dragontamer wrote:
             | Honestly, Eneloop's advantage is overstated these days.
             | 
             | Amazon Basics is likely an older Eneloop design for example
             | (Panasonic makes eneloop, and seems to be making Amazon-
             | Basic NiMHs). Energizer's "AA Recharge" series is also LSD
             | these days, and probably easier to source than Eneloop.
             | 
             | Eneloop deserves credit for shifting the market-perception
             | on NiMHs a decade ago. But the other companies have caught
             | on and have created well functioning, low-self-discharge
             | chemistries of their own by now.
             | 
             | -------
             | 
             | I'd recommend "whatever is cheapest to ship to you".
             | Energizer mostly for me, since I buy from Walmart / Home
             | Depot (etc. etc.). A lot of people buy from Amazon, so
             | "Amazon Basics" tacked onto your next order is probably a
             | good idea.
             | 
             | Eneloop commands a higher price and has some advantages.
             | But I find that Energizer / Amazon Basics are both good
             | enough for me.
        
           | Gigachad wrote:
           | One interesting solution I saw was batteries which stick a
           | lithium battery + charge controller / voltage adapter inside
           | the AA package so they can be used on any device.
        
           | justinator wrote:
           | Thankfully my not so new handheld Garmin GPS unit has a
           | specific NiMH battery mode. I'm sure it just changes the
           | algorthm slightly to work with the NiMH's discharge rate.
        
           | dragontamer wrote:
           | > Newer appliances have solved these problems. For example,
           | the Yamaha PSS-A50 (a fantastic, inexpensive portable
           | keyboard) has an option to configure the low-battery
           | indicator for alkaline or NiMH chemistry.
           | 
           | Different NiMH chemistries have slightly different voltage
           | curves.
           | 
           | Its an insidious problem. Different brands of NiMH just
           | discharges in a "flat" manner, and all of them are at
           | slightly different voltages. The electronics assume a voltage
           | curve of Eneloop (typically, since Eneloop is the most
           | popular NiMH brand), and other brands with their slightly
           | different voltage-curves will throw it off.
           | 
           | -----------
           | 
           | I find it more important to locally source NiMH batteries
           | (ie: what I can buy from Walmart / Home Depo down the street,
           | rather than paying for Amazon shipping) rather than
           | standardizing upon the Eneloops that everyone else is buying,
           | lol.
           | 
           | When I need a new AA cell, I buy it in my typical shopping
           | runs, rather than waiting for shipping. I don't care enough
           | about the voltage-curve problem to mass buy Eneloops yet. I
           | largely just accept that the "low-battery" indicators are
           | perpetually wrong.
        
         | vzaliva wrote:
         | I've switched to rechargables for home electronics years ago.
         | It makes me feel better doing my share of lessening environment
         | impact caused by disposable cells.
         | 
         | One notable exception for which I am still buying alkaine
         | batteries is the August Smart Lock. When using NiMH batteries
         | it starts complaining about depleted battery in a week, while
         | it still Ok and works for much longer. It was reported to them
         | and they advised to us alkaine. This is very annoying because
         | all they need to do is to fix the software which does the
         | voltage check and generates annoying notifications to the
         | users. Just a few lines of code (or maybe single constant)
         | could have an immence environment impact.
        
           | Scoundreller wrote:
           | I think this explains the problem, though If you could
           | configure the battery type, a software fix would work:
           | 
           | https://news.ycombinator.com/item?id=29910710#29912483
        
         | zwieback wrote:
         | I agree, rotating collection of charged cells is the way to go
         | but:
         | 
         | - need to establish a system of keeping track what's charged
         | 
         | - train family to participate
         | 
         | - train family to stop buying alkaline (mainly because in the
         | alkaline recycling process you'll lose a lot of your eneloops)
         | 
         | - grow immunity against complaints from family
        
           | PragmaticPulp wrote:
           | > - need to establish a system of keeping track what's
           | charged
           | 
           | This seems to be the root of all of your problems.
           | 
           | Just charge all of the cells that aren't in use.
           | 
           | When you take drained cells out of something, they go in the
           | charger.
           | 
           | Charger is always plugged in and right next to where you
           | store the cells.
           | 
           | If there's ever any question, just stick the cells in the
           | charger. Don't bother playing all of the games to avoid
           | "memory effect". It's much better with modern cells and not
           | worth the hassle to try to work around.
        
             | devnulll wrote:
             | The good chargers hold 8-16 batteries, so there's always a
             | set on there being charged. The chargers seem electrically
             | smart and maintain the batteries well.
             | 
             | This process works wonderfully. We've got ~100 Enloop's of
             | various generations around the house in TV Remotes, XBox
             | Remotes, Garage Door openers, and toys. This process works
             | well.
        
         | r00fus wrote:
         | Not to mention a LOT of items now come with non-removable
         | (mostly rechargeable) Li-Ion or NIMH batteries. Even small toys
         | which used to require external batteries now come with it.
         | 
         | So I still have a small stack of alkaline batteries from 2017 I
         | haven't replaced or depleted. Hopefully that stack remains
         | untouched for another few years as well.
        
         | mikepurvis wrote:
         | Replying to boost this. We love Eneloop and have probably 40-50
         | of them in the house at this point, between remote controls,
         | gamepads, children's toys, fairy lights, bike lighting, tools,
         | etc etc. They all get funneled through a La Crosse charger with
         | a simple two-bin depleted/charged system.
         | 
         | We've been buying them for years and I think I've only ever
         | disposed of one that was unwilling to take a charge.
        
         | lmilcin wrote:
         | I design some electronics in my spare time. As a user, I
         | strongly prefer to have a choice of using a rechargeable
         | battery. It somehow does not feel right to throw out a toxic
         | battery when I could have another type potentially hundreds of
         | times over many years.
         | 
         | It helps that there is a proliferation of quite powerful, low
         | voltage, low power chips.
         | 
         | Some of the devices I design have USB interface which gives
         | another option of charging the battery while it is connected.
         | 
         | I am currently working on a fully programmable mechanical
         | USB/Bluetooth keyboard. It will work off of two AA NiMh
         | rechargeable batteries and I plan these to be recharged any
         | time the keyboard is connected to the computer.
        
           | dragontamer wrote:
           | I'd assume that 3-cells could lead to a simple trickle-charge
           | circuit?
           | 
           | 3*1.35 == 4.05V, which is pretty close to the 5V power that
           | you take from the USB, seems like there's enough room to get
           | a regulator to turn 5V into a simple charging circuit.
           | There'd also be enough output to probably run 3.3V circuits
           | with a simple regulator.
           | 
           | 4*1.35 == 5.4V, which is beyond the capacity for 5V to charge
           | (unless you got a boost-converter).
           | 
           | ---
           | 
           | 2-cells == 2.7V, which means you probably need a boost-
           | converter to convert the battery-pack into something useful?
           | 
           | Not that I'm the designer or anything, but I like discussing
           | these issues :-) I haven't done any electronics since my
           | college days.
           | 
           | What voltage does the device operate at? The main cutoffs
           | these days seem to be 1.8V, 3.3V, and 5V right? 3-cells and
           | targeting 3.3V + charging from a USB (at 5V) seems like the
           | most obvious cutoff to me personally.
        
             | lmilcin wrote:
             | Newer STM32 lines go as far down as 1.7V. Or they would if
             | I was able to find other chips (notably Bluetooth) that
             | would suit me and could pull the same trick. As it stands,
             | the circuit can work down to ~1.85V which is still quite
             | comfortable with two cells.
             | 
             | I admit there is no particular reason to use 2 cells where
             | I could use 3 (they would still fit comfortably inside
             | keyboard enclosure). The only reason is vanity -- I hope it
             | will look sexier to other EEs:)
             | 
             | I dislike built in cells. I like ability to just change
             | batteries rather than have to plug in to charge. Nothing
             | worse than a peripheral like headphones that you have to
             | stop using just because charge ran out. Why do I need to
             | finish my couch session just because my keyboard can't take
             | a simple AA battery or two? Seems like completely
             | unnecessary nuisance.
             | 
             | Also, if you are talking about cell voltage, you need to
             | remember they loose voltage very quickly upon discharging
             | and most of the discharging happens at much lower than max
             | voltage. For NiMh you really want to make sure that your
             | circuit works with at least 1.2V per cell (as an absolute
             | minimum, in perfect conditions of room temperature and very
             | low discharge). Any higher than that and you aren't
             | actually discharging the cells properly and are not using
             | their capacity.
             | 
             | If your circuit works in short bursts of high current or
             | can be used outdoors, be prepared that the voltage can drop
             | very quickly especially when the cell is older (has been
             | through a lot of cycles).
        
         | jandrese wrote:
         | Most of my remotes are still using the batteries they shipped
         | with. It's hard to make the case for replacing batteries when
         | the originals last 15+ years (and counting).
        
           | Gigachad wrote:
           | A youtuber I watch recently made the case that NiMH batteries
           | should be used for _all_ uses because alkaline batteries will
           | eventually burst and spew acid over your electronics. Sounds
           | like it could take a very long time to do that, but it makes
           | sense just for the preservation of the device to use NiMH.
        
         | divbzero wrote:
         | I finally switched to Duracell's rechargeable NiMH batteries
         | last year and won't be going back to alkaline. They work well
         | even for things like flashlights that need low self-discharge,
         | and I no longer feel like I'm creating waste every time I burn
         | through a battery.
         | 
         | I also came across some rechargeable lithium batteries packaged
         | in 1.5V AAA, AA, C, D form factors, but they appeared to be
         | newer and I was unsure about long-term reliability.
        
           | piyh wrote:
           | The only thing I keep disposable batteries for is my key code
           | door lock
        
       | SavantIdiot wrote:
       | +1 for introducing me to the B&K 8600. It never occurred to me to
       | search for a DC load device. I've been building FET-based loads
       | and using a power supply to calibrate them. /smacks forehead/
       | This is what you miss when you don't get to work with
       | professionals on your hobbies (i.e., building low power IoT
       | sensors for funsies).
        
       | symby wrote:
       | Not included in this analysis is leakage rate... by which I mean
       | ooze leakage.
       | 
       | I have found that some batteries have a much greater likelihood
       | of leaking ooze than others (yeah Rayovak, I'm looking at you!)
       | 
       | Except in the case of crappy toys, the damage that this causes
       | radically outstrips the cost of the battery.
       | 
       | As a result, I buy batteries not based on electrical performance,
       | but track record in not ruining the things I put them into. I am
       | very happy to accept 50% less energy if I can avoid destroying my
       | $200 gadget.
        
         | mitchbob wrote:
         | > As a result, I buy batteries not based on electrical
         | performance, but track record in not ruining the things I put
         | them into.
         | 
         | So do I. I'm now using low self-discharge NiMH batteries
         | (mostly Eneloops) in pretty much every device that uses
         | batteries, and I've never had one leak. I also use smart
         | chargers to check battery health when I recharge them. A bit
         | more initial outlay, but much cheaper in the long run, as the
         | batteries can be recharged 1000s of times, and they hold their
         | charge for many months.
        
       | jvanderbot wrote:
       | Does anyone know of a good rechargeable battery comparison test?
       | I've noticed that some 18650's are just crap after a couple
       | charges, and some dinky AA batteries last forever after many
       | charges.
        
         | SomewhatLikely wrote:
         | Project Farm has a video with tests:
         | https://youtu.be/-jXQNY6rve8
        
         | arendtio wrote:
         | I am very happy with my Eneloops. I used Ansmanns before (and
         | still use the Ansmann recharge device), but they died after
         | like 20 cycles (note: those Ansmanns were models from before
         | the low-self-discharge era).
         | 
         | The Eneloops are 3 years old and still work fine while being
         | used every day (recharge about once per week).
        
         | 0cVlTeIATBs wrote:
         | https://lygte-info.dk is a good site.
        
         | aidenn0 wrote:
         | Amazon Basics low-self-discharge batteries are fine.
         | 
         | Eneloop if you want to avoid giving Amazon money and don't mind
         | paying more for the brand.
        
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