[HN Gopher] Researchers successfully convert methane gas into li...
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       Researchers successfully convert methane gas into liquid methanol
        
       Author : geox
       Score  : 39 points
       Date   : 2022-10-01 14:41 UTC (2 days ago)
        
 (HTM) web link (scitechdaily.com)
 (TXT) w3m dump (scitechdaily.com)
        
       | TSiege wrote:
       | This is just greenwashing so long as the source of Methane is
       | from fossil fuels. This article is doing a lot of work to cover
       | up this fact. The article says, "Despite the fact that natural
       | gas is a fossil fuel, its conversion into methanol produces less
       | carbon dioxide (CO2) than other liquid fuels in the same
       | category." Before we get into "other liquid fuels", if it comes
       | from the ground it's dirty. We have to be 100% clean energy if we
       | want a habitable planet.
       | 
       | Secondly it goes on to say "methane collection from the
       | atmosphere is critical for mitigating the negative consequences
       | of climate change since the gas has 25 times the potential to
       | contribute to global warming as CO2." This is a bullshit
       | suggestion with atmospheric methane levels still measuring in the
       | parts per billion range.
       | 
       | Just disingenuous and uncritical reporting all around
        
       | blueflow wrote:
       | How is this better, climate wise, than burning the methane
       | directly? Methanol still has the same amount of carbon in it.
        
         | anonporridge wrote:
         | It's not, if you assume the methane is burned completely. But
         | it's being discovered that simply flaring methane isn't as
         | efficient as previously thought,
         | https://arstechnica.com/science/2022/09/oil-industry-flaring...
         | 
         | So, unless you're running the methane through a generator that
         | burns it much more efficiently, like bitcoin miners are doing,
         | we'd be better off bottling it up as methanol where it can be
         | burned efficiently elsewhere.
         | 
         | The bigger impact is that it potentially creates a profit
         | incentive to capture waste methane, so it's less likely that
         | producers will cut corners and just let it vent. Why vent money
         | into the atmosphere?
         | 
         | The open question is whether conversion to methanol and
         | transportation will be cheap enough to actually generate a
         | profit. If not, then it will be better off just getting burned
         | on site.
        
           | blueflow wrote:
           | > we'd be better off bottling it up as methanol where it can
           | be burned efficiently elsewhere.
           | 
           | Liquid gas is compressed methane, and some industries and
           | cars already run by burning it. So the infrastructure already
           | exists.
        
             | anonporridge wrote:
             | You mean liquefied natural gas? Yeah, that's doable, but as
             | Europe is finding out right now, it's very expensive. You
             | have to keep the liquefied gas sufficiently chilled all
             | through transport. You wouldn't have to do that with
             | methanol.
        
               | blueflow wrote:
               | I mean liquefied methane, which does not need to have
               | fossil sources. It is also generated by biomass
               | facilities who operate on farm waste.
               | 
               | > You have to keep the liquefied gas sufficiently chilled
               | all through transport
               | 
               | No, just compressed. Same as with hydrogen.
        
               | scythe wrote:
               | The vapor pressure of methane is about 6.25 MPa. For
               | comparison a bike tire has about 0.4 MPa, a car tire
               | closer to 0.2-0.25. So you need a pretty damn good
               | compressor and pressure vessel / pipeline, versus a
               | simple tank for methanol. Also worth noting that the
               | methanol can later be easily converted to dimethyl ether
               | and used as a clean _er_ -burning diesel fuel (vapor
               | pressure ~0.5 MPa), where it may be possible to convert
               | existing engines:
               | 
               | https://www.frontiersin.org/articles/10.3389/fenrg.2021.6
               | 633...
        
               | MayeulC wrote:
               | I haven't read TFA yet (edit: as I thought, it's very
               | light in details), but I know it's a hassle to spring up
               | gas distribution logistics where it's only a secondary
               | product (oil wells). The question is: is this new method
               | simple enough to put in practice at production sites?
        
         | barbazoo wrote:
         | The methane won't spend all that time in the atmosphere acting
         | as a GHG much more potent than CO2.
         | 
         | > Furthermore, methane collection from the atmosphere is
         | critical for mitigating the negative consequences of climate
         | change since the gas has 25 times the potential to contribute
         | to global warming as CO2, for example.
        
           | blueflow wrote:
           | > In the study, the scientists used pure methane, but in the
           | future, they will extract the gas from renewables such as
           | biomass.
           | 
           | No extra capture.
        
           | [deleted]
        
       | dimitar wrote:
       | Unfortunately, this might as well mean more natural gas
       | extraction and the availability of a cheap fossil fuel. This is
       | why we also need carbon taxes; technology developments can impact
       | the fight against climate change in unpredictable ways.
        
       | anonporridge wrote:
       | This may make it easier to bottle up and sell the methane gas as
       | fuel so it can be burned efficiently elsewhere, since
       | transporting gas from remote locations is very hard and
       | expensive, either in pipelines or chilled and liquefied. Still
       | ends up as CO2 in the atmosphere, but that's drastically better
       | than methane, which eventually reacts into CO2 anyway after
       | decades of 10-80x warming.
       | 
       | This is especially true at the many sites that produce very
       | small, but collectively significant, amounts of methane,
       | specifically landfills (check Vespene Energy, a startup in
       | California targeting this problem [0]).
       | 
       | So, this is potentially a fantastic development because it could
       | create a profit incentive to completely capture waste methane
       | rather than at best flaring it (which has been found to only be
       | about 91% efficient in practice [1]) or at worst simply venting
       | it. Right now, the only incentive to even flare methane is
       | general goodwill or fear of the stick of regulation. A carrot to
       | generate money along with the stick of fines would be a much more
       | powerful force to actually reduce the impact, especially in most
       | of the non western world that don't have a very strong stick.
       | 
       | [0] - https://twitter.com/Digital_Ore
       | 
       | [1] - https://arstechnica.com/science/2022/09/oil-industry-
       | flaring...
        
         | sfink wrote:
         | I wonder how efficient the conversion in the article would be,
         | after being adapted to real world "dirty" methane instead of
         | pure.
        
           | anonporridge wrote:
           | That is something I mentioned in another comment below.
           | 
           | It's still an open question whether conversion to methanol,
           | transportation, and sale will be cheap enough to actually
           | generate a profit. It the real world, it might simply cost
           | too much or be too dirty of a conversion that the numbers
           | don't add up.
           | 
           | In this case, then we will still be better off just burning
           | it efficiently on site.
        
       | im3w1l wrote:
       | How much sense would it make to do solar -> hydrogen -> methane
       | -> methanol?
        
         | coderenegade wrote:
         | I don't think you need to go through methane to get from
         | hydrogen to methanol, you just synthesize methanol directly
         | once you have the hydrogen. In fact, most methanol is made by
         | splitting hydrogen from natural gas first.
         | 
         | This is more useful for producing methanol from biogas (i.e.
         | waste facilities), since the gas is produced by bacteria as
         | part of the natural decay process. It's an alternative to
         | producing methane catalytically from hydrogen.
        
         | Puradolia wrote:
         | There's no reason to do that. You do not want to create more
         | methane, and the possibility of even a trickling of it getting
         | into the atmosphere. This methane to methanol is purely to get
         | rid of the methane we produce, and hopefully the methane stored
         | in the atmosphere. We've got plenty of hydrogen, it's one of
         | the most common elements (iirc) in the known universe, but to
         | convert some into methane? Hydrogen is clean, and then make it
         | toxic methane? It's much better to just use the hydrogen as
         | fuel. I remember seeing an article one time about a method to
         | convert hydrogen into fuel, and so it's much better to do it
         | that way. Though how costly or doable on a mass scale either
         | conversion is, we don't know yet.
        
           | TimJRobinson wrote:
           | This would be an alternative source of methane rather than
           | getting more from the ground. If we could recycle the carbon
           | in the atmosphere + hydrogen from water we could use this
           | wherever methane is used currently without needing to make
           | new vehicles / aircraft etc that run on hydrogen.
           | 
           | This is a good article about it:
           | https://caseyhandmer.wordpress.com/2022/07/22/were-going-
           | to-...
        
           | labster wrote:
           | Methane is not toxic, in fact it's frustratingly inert.
           | Leading to long atmospheric residence time in decades. Unless
           | you meant to type toxic methanol, which is true, but it's not
           | that toxic. Just don't drink the wood alcohol, okay?
           | 
           | I think the plan is to produce methane from hydrogen on Mars
           | for the return trip on Starship. Kind of a niche case,
           | though.
        
       | aaron695 wrote:
        
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