[HN Gopher] The biggest EV battery recycling plant in the US is ... ___________________________________________________________________ The biggest EV battery recycling plant in the US is open for business Author : orangebanana1 Score : 332 points Date : 2023-04-10 15:38 UTC (7 hours ago) (HTM) web link (www.canarymedia.com) (TXT) w3m dump (www.canarymedia.com) | atleastoptimal wrote: | The moment I read this headline I went straight to comments to | find the 20 people decisively declaring it completely useless. | Classic HN | HopenHeyHi wrote: | [flagged] | jamespo wrote: | Why should anyone spend their time trying to persuade a 20 | day old account on here? | HopenHeyHi wrote: | Look at the numbers and think it through on your own, don't | need to persuade me or anybody of anything. You should do | that if you care whether or not the idea/numbers add up at | all for your own sake. Persuade yourself. As you care about | the truth. | | Right? | | .. | [deleted] | nicenewtemp84 wrote: | I wonder how they are able to shred batteries safely, but we hear | that an accident that leads to pack deformation can easily start | a massive fire. | vrglvrglvrgl wrote: | [dead] | Tagbert wrote: | There are other companies working on these processes. | | US increases EV battery recycling capacity with new AL facility | processing up to 10K tonnes annually | https://electrek.co/2022/10/14/us-increases-ev-battery-recyc... | | Redwood Materials recovers ~95% of metals from EOL battery packs | https://www.teslarati.com/redwood-materials-metal-recovery-e... | m463 wrote: | A lot of old ev batteries are snatched up by people who want to | use them in whole-house battery systems. | | I wonder if recycling of ev batteries might be premature for some | or many cells? | jeffbee wrote: | A lot? I bet the number of EV battery packs that have been | turned into whole-house batteries by individual homeowners is | in the single digits and might be zero. | jaberabdullah wrote: | [flagged] | jaberabdullah wrote: | [flagged] | xeromal wrote: | Glad my homestate is making decent strides towards building new | things. We just had a nuclear reactor come online, a rivian EV | truck factory is here, and now this. We do a bunch of naughty | things but I can be proud of these at least. | cpursley wrote: | There's a bunch of new plants and factories going up in Georgia | (maybe there's a comprehensive list somewhere). Definitely | bodes well for Georgia's future in terms of economics. | xeromal wrote: | Yeah, the news is pretty non-stop of new things opening up. | Atlanta trying to become the new hollywood I think | kickstarted all this at least in my head timeline but I'm | sure some hardworking business owners and politicians really | just focused on bringing in new work. | blamazon wrote: | I think it goes a lot further back, one semi-serious data | point: the "Chamber of commerce runs Atlanta" meme was | satirized by the TV show Futurama in the year 2000: | | https://en.wikipedia.org/wiki/The_Deep_South_(Futurama) | | https://youtu.be/LeYihjMo0Bk | megraf wrote: | This is likely due to GA's extensive rail network[0]. | | [0] - | https://opendata.atlantaregional.com/datasets/GARC::railroad... | kfajdsl wrote: | Man, if only we could use some of that for passenger rail... | Being able to go from Atlanta to Savannah without a car would | be awesome. | Analemma_ wrote: | It's a nice idea but keep in mind that any freight which | gets displaced from rail thanks to passenger cars would | have to go by truck instead, probably with a massive | increase in net emissions. Having passengers and freight | share track in the US is probably not a win for the | environment; passengers would need separate track instead. | KennyBlanken wrote: | You have that backwards. Low occupancy vehicle travel is | the most wasteful form of personal transit. | | Rail passengers displaced by freight become low occupancy | vehicle trips. | | In my state, a commuter rail coach car has about 180 | seats. Let's be cautious and assume 50% occupancy. | | That's 90 people, and based off the US passenger car | fleet averaging 25mpg, they collectively would have used | 3.6 gallons of gas per mile. | | An eighteen wheeler gets 5-10 miles per gallon. | | Even assuming just 5mpg, the passengers in that one coach | car would have used _eighteen times more fuel_ than the | truck hauling a container would. | | Furthermore: freight and passenger use of rail are not | mutually exclusive uses. Freight is in theory far less | sensitive to scheduling, and like a lot of trucked | freight, can happen during times passenger use is low. | But because industry has squeezed their supply chains to | the hair of breaking under "just in time delivery" to | minimize warehouse space and the like...which bit us | pretty severely in the pandemic...freight companies are | optimizing for shareholder profits and own the tracks. So | they prioritize their freight over passengers. Result? | Passenger service is riddled with service issues, leading | to less passenger use, which is fine as far as the | freight companies are concerned, because they can move | more freight. | | The core problem is that critical infrastructure is being | run privately by for-profit publicly traded companies. | TYPE_FASTER wrote: | Adding passenger traffic does not necessarily require | displacing freight traffic. | | Here's a document that contains a map of current rail | density: https://www.dot.ga.gov/InvestSmart/Freight/Georg | iaFreight/Ta... | elif wrote: | But things like "okay now wait on this random section of | tracks for 3 hours because of a pass and traffic down | stream" are routine on freight lines, but obviously not | desirable for passenger rail. | babypuncher wrote: | So you build more rail | JumpCrisscross wrote: | > _build more rail_ | | Passenger rail doesn't tend to break even on long- | distance dedicated routes, even taking into account | externalities. | bluGill wrote: | But it does very well at medium distances while you find | all over. | JumpCrisscross wrote: | > _it does very well at medium distances_ | | Depending on density. I'd wager the Atlanta metropolitan | area is just about crossing that threshold, _i.e._ they | should built it now. | danielvf wrote: | Atlanta does have trains, and in fact has the 8th most | annual riders of any US city, right behind the Bay Area. | | https://en.wikipedia.org/wiki/MARTA_rail | JumpCrisscross wrote: | I guess MARTA is between municipal and regional rail, | sort of like BART. I meant for connecting the Atlanta | metropolitan area to its region, not intraconnecting. | elif wrote: | 91,000 daily riders according to that link | | 2,000,000 daily vehicles on this Atlanta transit system | | https://en.m.wikipedia.org/wiki/Interstate_285_(Georgia) | bluGill wrote: | Roughly speaking the density of the US east of the | Mississipi and the far west coast is dense enough. The | rocky mountains and Alaska really bring our average | density down. | grogenaut wrote: | In like 1/3rd or less of the land mass of the us yes. | iknowstuff wrote: | It doesn't have to. How much do our freeways cost us? esp | with externalities? | waterheater wrote: | >How much do our freeways cost us? esp with | externalities? | | Rail also has cost, including externalities. For example, | as a wise person on the Internet once said, "Trains take | you from a place you don't live to a place you're not | going to." The "last-mile problem" is a non-trivial | factor to building train networks which by definition is | not solvable by more rail. | | You're considering a cost analysis. A more complete | analysis is the benefit-cost analysis (BCA). If the | benefits outweigh the costs, the project is a net | positive for society. Asking only how much our freeways | cost us avoids consideration of the known benefits. | Here's a BCA from 2021 which investigates a highway | project, so you can see exactly how much freeways benefit | and cost us: | https://www.mdot.maryland.gov/OPCP/I-81BCA_Report.pdf | | >It doesn't have to. | | That's a nice sentiment, but sometimes the energy | required to reform is higher than expected losses. The | entire Amtrak network is kept afloat because of a handful | of lines in New England between DC, New York, and Boston. | Amtrak basically runs a loss everywhere else. | mschuster91 wrote: | > The "last-mile problem" is a non-trivial factor to | building train networks which by definition is not | solvable by more rail. | | The trivial answer is to build out last-mile services: | trams, buses, actually usable bike lanes, and something | that could perfectly well work in US suburbia hell (wide, | but barely frequented streets): automated "people | movers". | waterheater wrote: | You say last-mile services are trivial, but they | absolutely are not trivial in the slightest, and assuming | they are demonstrates a fundamental lack of understanding | of how change gets made in a democratic, even republican, | manner. | | Changing the primary transportation mode of a population | requires a cultural shift to adopt the new mode. The | population must be willing to forgo what they already | have in favor of something new. You are saying that | automated "people movers" (which is an emotional sketch | rather than an defined policy item) will work well in | car-ubiquitous US suburbia, but these folks live in | suburbia specifically because of low population density | and general quality-of-life. They explicitly enjoy being | around people they know and not being around people they | don't know. Any solution you're proposing must respect | their existing values while providing an alternative | option. | | Your examples of last-mile services aren't really last- | mile services, save for the final one: | | >trams | | Since it seems infeasible to allow anyone to board a tram | at any point on its journey, tram stops will be | necessary. Perhaps you now face a last-quarter-mile | problem, which is better but still may not be good enough | for that specific population. Track maintenance may be | significantly lessened by using a "trackless tram", but | such would have severe challenges in a snowy climate. | Trams only work in dense urban environments. | | >buses | | Buses have been used in cities for many decades, so our | understanding of them is that they work generally well. | Buses are common in suburban environments with many low- | income residents. The benefit of buses is their limited | amount of supporting infrastructure and route | adaptability. However, similar to the tram situation, a | bus still does not get you directly to your home. | | >actually usable bike lanes | | Bike lanes in dense urban environments are almost always | a net positive. What constitutes an "actually usable" | bike lane depends on an individual's risk tolerance. As a | last-mile problem, not all people are physically able to | bike from a train station, though ebikes do help. Again, | weather can impact people being willing to bike, let | alone leave the house. | | >automated "people movers" | | This service is more conceptual, but I imagine you're | thinking of a Waymo-style service, where you can summon | an autonomous vehicle which will pick you up at home and | take you to-and-from the station. The main issues here | are availability and reliability. If addressed, you'll | likely crack the suburban transportation nut, but such | individualized transportation in cities isn't | sustainable. | babypuncher wrote: | > Trains take you from a place you don't live to a place | you're not going to. | | Airplanes have the exact same problem, but I don't see | people saying we should stop investing in airports. | | For long distance travel, I don't think it's a huge | problem that you might need multiple modes of transit to | get all the way from A to B. | bluGill wrote: | Trains are too slow for long distance travel. They are | useful for short and medium distance travel, but for such | trips travel time to the station becomes more important. | If this isn't made convenient people will quickly decide | their car is better: it goes when they want to go, and | goes directly to where they want to be. | TylerE wrote: | Different model. Planes have much greater network | effects. Consider a trip between New York and Dallas. A | plane can fly a direct route, and will if there is much | demand. | | A train system can't do that... in my example you'll end | up either going South along the coast and then west | through New Orleans to San Antonio, and then back north | to Dallas, or the same but reach Mew Orleans via Chicago. | | Trains work well when there is a large central(ish) city | that can act as a hub? Like London, Paris, or Berlin. Not | so well in the US where the population is heavily biased | towards the outer rim, with a relatively a gaunt desert | of nothing in the middle. | waterheater wrote: | >Airplanes have the exact same problem, but I don't see | people saying we should stop investing in airports. | | Fair point. We should then see if air travel holds a key | advantage over rail travel in the USA. As I see it, the | answer is in both space and time savings, both of which | minimize cost and maximize benefit. The time savings are | particularly pronounced, especially over distances | greater than, say, a few hundred miles. Happy to | elaborate on the savings in more detail, if you desire | such. | | >For long distance travel, I don't think it's a huge | problem that you might need multiple modes of transit to | get all the way from A to B. | | That is, of course, your opinion. I'm sure there are | tens, if not hundreds, of millions of Americans who will | strongly disagree with you because they are, in no | particular order: feeble, disabled, terrified of a | particular mode of transit, hurried, cost-conscious, | traveling with multiple young children, etc. | cyberax wrote: | Freeways are amazingly cheap. 1 mile of new 6-lane | freeway on level terrain is about 3 million: | https://www.strongtowns.org/journal/2020/1/27/how-much- | does-... | | Amazingly, railroads are not much cheaper. The current | costs of tracks are estimated at about $2 million per | mile, and this is without taking into account all other | necessary rail infrastructure (such as sorting yards, | maintenance facilities, etc.). | | And CO2 emissions are being fixed by switching from gas | cars to EVs. | adgjlsfhk1 wrote: | The problem is that 1 mile of rail can move a lot more | passengers than 1 mile of road. | cyberax wrote: | The calculations on that page are not correct. First, the | average car occupancy is not 1, it's 1.5 on average. | Second, the lane capacity is 1900 cars per hour (that's | maximum at around 45 mph, btw). So this works out to 8550 | people per hour. | | A realistic scenario for commuter trains (that would | replace a freeway) is 1 train every 10 minutes, and even | this is pretty tough. So you have 6 trains per hour, and | to match the throughput you'd need 1425 people per train. | | Most train platforms are maxed out at well below 10 cars | (Caltrain is 6 cars), 20 car trains are just pure | nonsense for commuting. So for 10 car trains it'll be | around 150 people per car. Caltrain cars are 130 seats | per car ( https://www.greencaltrain.com/2014/05/keeping- | up-with-caltra... ), with another 40 standing places. | | Basically, a perfectly run commuter train system is | _just_ barely comparable with a regular 6-lane freeway. | | Sorry train fans, but trains are not that great for | commuting. | judge2020 wrote: | Correction, trains specifically. Subways and light rail | are immensely higher ROI (as in, benefit vs cost) within | a city since it effectively forces people close together, | while a 6-lane-on-each-side highway isn't economically | feasible for all of the high-traffic areas. | ProfessorLayton wrote: | BART has a capacity of 200 passengers per car in their | legacy fleet, 241-256 for their new fleet, and regularly | has 10 cars per train during peak hours [1] and travels | 80mph. | | [1] https://wbcapp.oaklandnet.com/cs/groups/public/docume | nts/pro... | richardw wrote: | > Sorry train fans, but trains are not that great for | commuting. | | Quick comparison: more people (3.6m) go through Shinjuku | Station in Tokyo than the daytime population of | Manhattan, at 3.1m. Only half of those travel into | Manhattan, using all modes of transport. When things get | extreme it's hard to just double the road network and | parking into a single location. | | https://en.m.wikipedia.org/wiki/Shinjuku_Station | sixstringtheory wrote: | What is the route capacity for a lane of freeway vs a | rail line? I assumed it's the opposite, since a freeway | has continuous throughout while a rail line is discrete, | but I don't have a good intuition for comparing the scale | of each mode. | dragonwriter wrote: | > What is the route capacity for a lane of freeway vs a | rail line? I assumed it's the opposite, since a freeway | has continuous throughout while a rail line is discrete | | According to this book (which provides assumptions and | calculations supporting) [0], 10:1 in favor of rail, as a | conservative estimate. | | https://eng.libretexts.org/Bookshelves/Industrial_and_Sys | tem.... | cyberax wrote: | > A rush-hour train may consist of 20 cars | | The author is smoking some hard crack. | AnimalMuppet wrote: | Well, BART has no problem running 9-car trains. I don't | know if that's rush hour or not, but I've seen them. If | the rest of the math is right, that still gets you | 4.5-to-1 in favor of rail. | bluGill wrote: | How do you calculate capacity? Safety engineers keep | yelling that drivers need to keep 3 seconds between cars, | but in reality they most drive about .3 seconds from the | car in front. There is nearly a 10x difference in freeway | capacity between just those two. | | Trains tend to maintain longer distances, but if you want | to ignore safety we can follow a lot closer. | ClumsyPilot wrote: | > And CO2 emissions are being fixed by switching from gas | cars to EVs. | | Not reall, rail is 9 times more energy efficient than | road vechicles. Thats why its cheaper to have a diesel | locomotove move freight than to pour the same diesel into | trucks. | | The whole reason rail exists is thsa its the most | efficient form of tranportation on land. | bluGill wrote: | There are a lot of assumptions in the idea that trains | are more efficient than road vehicles. Trains tend to | carry more heavy bulk goods like coal, if they had more | light things the numbers would change. Trains get a lot | of efficiency from running very long trains, but that | only works out when you have a lot of things going the | same way, if you had smaller trains from each warehouse | (which now is done by truck) that would reduce th | efficiency. | | Yes trains have some efficiency advantages, but in | similar service the difference is small. You only get | those advantages when you use trains for things that | trucks cannot do at all. | mikepurvis wrote: | The very long trains of mostly goods like coal are not an | inevitability, though-- it's a result of rail companies | implementing PSR in response to some pretty specific | incentives, see: | | https://www.nytimes.com/2022/10/09/opinion/business- | economic... | | A number of YouTube video essays argue the sides of this | as well, here's one based around Sen. Sanders confronting | a rail CEO in the wake of the recent Ohio derailment: | https://youtu.be/e4w0q5NzCwA | babypuncher wrote: | You're comparing dollars-per-mile of infrastructure when | the more important metric is dollars-per-passenger-mile. | You can build 1 mile of freeway for not much more than 1 | mile of rail, but that mile of rail can serve | considerably more passengers. | mikepurvis wrote: | Two other factors that aren't coming up in this analysis | are long term maintenance costs (highways in Ontario are | constantly being resurfaced) and land use opportunity | costs (it's simply not viable to run six lanes of freeway | into most CBDs, and doing it with grade separation leads | to raised highway eyesores or insanity like Boston's Big | Dig). | | In any case, as others have pointed out, we don't have to | argue hypotheticals here-- China, Japan, France, Germany, | etc have all shown that frequent-service electrified | passenger rail is perfectly possible and an incredible | public good. | samstave wrote: | Yah, but youre still in gorgia | xeromal wrote: | I grew up near one of those major lines, the one that goes | along 515. We used to try to get a train to flatten a penny | for us or race it on our fourwheelers. Never got a flattened | penny though. lol | bluGill wrote: | I used to get lots of flattened pennies. The trains throw | them so you have to spend a lot of time searching the | gravel around the tracks. Be sure to watch for other trains | so you don't get hit. | redundantly wrote: | Gotta tape the coin to the track so it doesn't rattle off | before the train gets to it, or use chewing gum. | xeromal wrote: | I was around 5 years old so my logic was pretty simple. I | think I tried a heavy rock lol | jeffrallen wrote: | Where the heck are they going to find feedstock? Renault found | that the batteries don't wear out, they just keep running, going | on 10 years. | to11mtm wrote: | I'm guessing at least some consumer batteries (i.e. | laptop/phone/ebike/etc) can also be recycled at the same | facilities; These are often of similar chemistry but may have | lower lifespans and there would be no reason the facility could | not process them. [0] | | [0] - A good example would be 18650 batteries; these are used | by Tesla but are found in lots of other things. | Ensorceled wrote: | I suspect, eventually mostly insurance writeoffs, wrecks etc. | mardifoufs wrote: | I guess the Nissan Leaf might single handedly provide for | enough initial feedstock, considering how quickly their | batteries degrade. Just awful battery management from Nissan on | that car. | foolfoolz wrote: | given the u. s. goals of evs and energy storage recycling | batteries domestically instead of shipping the metals off to | cheaper destinations is going to become a matter of national | security as we won't produce enough metals on our own | pkaye wrote: | The infrastructure bill had funding for domestic extraction and | processing of critical minerals. Also US has been encouraging | Canada to do the same including providing some grants to | Canadian companies to get started. Below is the list of | minerals. | | https://www.usgs.gov/news/national-news-release/us-geologica... | legitster wrote: | Super cool development. Love seeing people actually acting on the | laws of of supply and demand. | | > The scrap and used batteries go through mechanical shredding | and sieving, which produces "black mass." Ascend extracts lithium | carbonate from the mass; the remaining mass contains materials | such as graphite, nickel, cobalt and manganese. | | The article brags about the input, but is cagey on the details of | the about. Of the 30k tons processed in a year, what percentage | is reconstituted? | JumpCrisscross wrote: | We have a dearth of battery-grade metals refining in America. | Battery plants need specialised powders to do their work. Making | them isn't easy. | | Many aspiring refiners brand themselves as recyclers, since | turning metals and old batteries into battery-grade powder is | more similar than one would expect. (Lithium carbonate.) | Vt71fcAqt7 wrote: | That's interesting. Can you expound on this? | JumpCrisscross wrote: | > _Can you expound on this?_ | | Which part? | Vt71fcAqt7 wrote: | >turning metals and old batteries into battery-grade powder | is more similar than one would expect. | bluGill wrote: | I'm not really an expert, but one obvious thing is you | need to take non-pure metals and purify them. Recyclable | batteries fail when the chemicals instead chemically | combine with something other what you intend them to, | crystalize, or otherwise become not the pure metal you | start with. That impure metal is not conceptually | different from ore, and the same process to turn ore into | battery material must be done. | | Note that ore is more complex as you need to remove a lot | more non-battery stuff, while in a used battery what you | want is still in fairly high concentration, just not in | the form a battery needs. | samstave wrote: | As an ignoramous ; what is it about Lithium specificall | that makes it special to batteries? | | Is is that it freely ejects electrons at a higher rate | than other materials, given a certain catalyst? | bluGill wrote: | That was covered in my college chemistry class, but I | took it 25 years ago and don't really remember the | details. Electro negativity comes to mind, but I might | have the terms wrong. In any case the laws of chemistry | apply. | sethhochberg wrote: | Generally yeah - it is both willing to give up and take | back electrons pretty easily (so, discharging and | charging) but in the modern era another really important | factor is that it balances having these properties and | also being very light relative to the amount of energy it | can hold in a battery. Good for portable applications | like cell phones, cars, etc. | [deleted] | Scoundreller wrote: | Lithium is at the top, so you get the most voltage per | molecule. | | Then there's other factors like discharge recharge, | temperatures, all that, but lithium is basically the best | if you can get the other factors to play nice too: | | http://hyperphysics.phy- | astr.gsu.edu/hbase/Tables/electpot.h... | JumpCrisscross wrote: | Recycling batteries involves shredding them into black | mass [1] and then extracting lithium carbonate from it. | This is the same stuff lithium from mines and brine | fields is processed into [2]. (Carbonate is processed | into lithium hydroxide [3], the stuff we trade [4] and | mix in batteries.) | | In summary, they all start with pulverized stuff from | which lithium carbonate is extracted and turned into | lithium hydroxide. The fact that it's batteries versus | rock just changes the front end; nothing downstream could | care less. | | [1] https://catalysts.basf.com/blog/lets-talk-recycling- | what-is-... | | [2] https://samcotech.com/what-is-lithium-extraction-and- | how-doe... | | [3] https://en.wikipedia.org/wiki/Lithium_hydroxide | | [4] https://www.cmegroup.com/markets/metals/battery- | metals/lithi... | Waterluvian wrote: | Hmmm so they don't really disassemble the batteries. They | just grind them all up and then use physical and chemical | processes to filter the bits they want? | | I guess this makes sense at scale. I'm not sure what I | was picturing. | nine_k wrote: | I suppose they disassemble large racks of batteries, to | remove the strong structural metal which us hard to | shred, and maybe copper wires that are expensive. But not | farther. | | Individual cells are shredded, the cover metal is removed | by magnets, anything soluble is removed by water or other | solvents, whatever remains possibly may be further | processed, or can go safely to a landfill. | ClumsyPilot wrote: | Generally, all forms of recycling that reauire manual | dis-assebly don't really work. Labour cost is too much. | Broken and damaged items dont dissasemble. each itme is | unique, that sort of thing. Thats why plastic recycling | and electribics recycling doesn't work. | | Recycling of metals and glass succeedd because you can | just grind and melt everything. | Waterluvian wrote: | So when I'm asked to obsessively clean out my aluminum | recycling, I've always assumed that's just a favour to | their equipment. But surely the process expects FOD and | messy cans. | maxerickson wrote: | It's staged and transported. So like the less food there | is at the collection site the less stink and rodents | there will be. | yurishimo wrote: | I've always wondered this. In my small town in The | Netherlands, plastic and metal go in the same recycling | sack. They specifically state that you don't need to | obsessively clean the containers, but they should be | "empty". I'm sure I've accidentally tossed some paper in | there, but I assume that gets burned away at some point. | | But how they sort it afterwards? I have no idea. Not all | metal is conductive, though I have to assume they do some | magnetized sorting. Plastic can probably be blown away | for sorting further down the line. | | Might need to explore this more in the near future! | Scoundreller wrote: | My thought was the melting process burns most of it off | and then the ash gets skimmed off the top. | | not worth it to clean yourself. | dlkasajiewo wrote: | Nooooo! you can't use wikipedia as a source it's not | reliable >:( | | jkjk. Thanks for sharing! | boshomi wrote: | Shanghai Metal Market lists used Lithium-ion battery | material/battery scrap | | https://www.metal.com/price/New%20Energy/Used-Lithium-ion-Ba... | | About 95% of Lithium can be reused. | KennyBlanken wrote: | Adding to this, a reminder that lithium ion batteries contain | very little lithium, and it's not elemental - an extremely | common misconception leading to people thinking that they can't | use water to stop a pack undergoing thermal runaway / on fire - | something that can _only_ be stopped via the cooling effect of | water. | samstave wrote: | So aside from the lithium, what is causing the runaway | thermal to fire/explosion?? | [deleted] | rootusrootus wrote: | The electrolyte is very flammable and a short circuit | provides the temperature to ignite it. Some lithium battery | chemistries (LFP is probably the most common, but LTO as | well) are much less likely to burn when they fail | catastrophically. | boshomi wrote: | Nickel and Cobalt. This metal oxids creates molecular | oxigen. | | This oxygen feeds the fire and make it hard to fight. | | Lithium iron phosphate do not show this kind of reaction. | peteey wrote: | Yes and no. Lithium metal is the highly reactive element | in batteries. | | Similar to Hydrogen and Sodium, elements in the first | column of the periodic table are highly reactive | (flammable) because they readily give away their single | electron in the outermost orbital. | | Some Lithium battery variants might have marginally safer | properties, but they are fundamentally volatile at full | charge. | philipkglass wrote: | Commercial lithium ion batteries do not contain metallic | lithium in the charged or uncharged state. They have | lithium ions intercalated into the anode material in the | charged state. | | Primary (disposable) lithium batteries do contain | metallic lithium in the charged state, and there are | efforts to develop rechargeable batteries using pure | lithium metal at the anode. Rechargeable batteries that | contain metallic lithium anodes would be able to store | more energy, but they are also more hazardous and | currently have low cycle life. | decide1000 wrote: | Is this different from how they recycle EV batteries in Europe? | ChancyChance wrote: | How many EV batteries are decommissioned each year, i.e., could | be recycled? This company can handle 70,000 per year according to | the article, but what is that number out of? | | Side note about consumer lithium batteries: The nearest lithium | recycling near me is 40 miles away, and it costs $$ to drop of | your stuff. I can afford that, but I doubt most Americans | properly dispose of their batteries. Heck, I have a neighbor who | burns his trash near the road and one time saw him burning a few | car batteries in the pile. | theshrike79 wrote: | Not many. Not including a few larger recalls (Hyundai Kona for | example), the battery replacement percentage for EVs is under | 5%. The rest are still running on the original battery.[0] | | This is the biggest limit for re-using and recycling EV | batteries, the damn things just won't die. | | [0] https://www.businessinsider.com/electric-car-battery- | models-... | elihu wrote: | From the article, they actually get most of their waste | material from battery factories, which is interesting. | | > "That's not to say there are enough old batteries coming in | to fill the factory. Currently, 80 to 90 percent of what's | going into Ascend's Covington facility is scrap materials from | battery factories, including SK Battery America's plant in | Commerce, Georgia." | | Eventually we'll have a lot more end-of-life batteries, but for | now most of the EV battery packs that have ever been made are | still in the middle of their respective bathtub curves. | acyou wrote: | Pretty pathetic "recycling": 1. 80-90% of input is not even | batteries, it's scrap from woefully inefficient and low yield | battery cell manufacturing 2. "Recycling" consists of mechanical | shredding to combine all of the copper, aluminum, steel, cathode | materials, anode materials 3. A single extraction process pulls | out lithium carbonate, the rest is saved for the future as "black | mass" for as yet nonexistent processes to pull out the valuable | cobalt, nickel, manganese, phosphorus, graphite. | | The approach taken is practical, but kind of stupid. We want to | physically separate these materials, so let's grind them into a | well mixed aqueous slurry, then let the process chemists loose to | solve it with science. | | Particulate contamination of new or recycled battery materials | with iron particles is a particular concern. Grinding the steel | battery casings will not help. | | The failure isn't with the battery recyclers, we shouldn't blame | them. The issue is that consumers pay $0.05 per cell to recycle | cells which at the moment are not recyclable, and we all see it | as OK. I got my Tesla, ... you. So, as a result, there is zero | incentive to consider the full product life cycle when designing | cells. | toomuchtodo wrote: | Input volume is low because vehicle batteries last forever. | Importantly, we can ramp on QA rejects, salavaged vehicles, etc | before there are tens of millions of EVs out there (not to | mention stationary storage that will eventually EOL) needing | waste management. Slow is smooth, smooth is fast. | | https://cleantechnica.com/2022/09/21/surprise-nissan-leaf-ba... | | Not super familiar with Ascend ground truth, but very familiar | with Redwood Materials state of the art. | mikestew wrote: | _Input volume is low because vehicle batteries last forever._ | | I am not sure of your meaning. Because, taken literally, our | 2011 Nissan Leaf would like a word with you. | kccqzy wrote: | I'm guessing the battery in your Nissan Leaf only has maybe | 60% of its capacity when new? That's not so bad that a | battery would be deemed unusable. If you didn't want that | battery, that battery probably would not end up in a | recycling site but reused in other low energy-density use | cases. | greenthrow wrote: | My 2014 Nissan Leaf still had great battery life when we | finally traded it in last year. | | Often times a Leaf's entire pack can substantially recover | capacity by replacing a single problematic cell. | r00fus wrote: | Nissan for whatever reason never chose to do (and still | doesn't do in 2023) active battery thermal management that | every other EV manufacturer does - I have a Ford Focus EV | (2017) and despite being a complete econobox compliance | vehicle (which I still love) it actively manages battery | heat. | | Luckily Leafs are a minority of all EVs so the point still | stands - EV batteries will likely outlive the car. | nkingsy wrote: | OG leaf battery design was legitimately flawed. | | I had one for a while and watched the range drop from 50-40 | "miles" (half that really) over less than 10k miles of | usage before I sold it. | nicenewtemp84 wrote: | Chevy Volt batteries are holding up great even in 2012 | models. There are definitely people experiencing failures | of a cell leading to bricking the car, or even a temp | sensor failure in the pack leading to the vehicle bricking | itself, but for 95%+ of people it seems like a decade old | battery is doing great. I've got 170k miles on my decade | old Volt and everything seems good as new for now. | rootusrootus wrote: | I figure that over 10 years later, the fact that the only | example that consistently comes up is the Nissan Leaf means | we've made excellent progress on EV batteries. It's the | exception proving the rule. | outworlder wrote: | > Because, taken literally, our 2011 Nissan Leaf would like | a word with you. | | 2011 was a particularly bad year for the Leaf. And they | were not great (battery life-wise) before 2015 ('lizard | pack'). | | The newer ones are faring much better. Sure, this is of no | consolation for your Leaf, but I'd keep an eye for a | battery pack from a Leaf that's totaled for other reasons | (minor accident causing airbag deployment, for example). | You can even add a larger battery than the one your model | came with. | toomuchtodo wrote: | > Many will be amazed to learn that Nic Thomas, Nissan's | marketing director for the UK, told Forbes recently, | "Almost all of the [EV] batteries we've ever made are still | in cars, and we've been selling electric cars for 12 years. | We haven't got a great big stock of batteries that we can | convert into something else," he added. "It's the complete | opposite of what people feared when we first launched EVs | -- that the batteries would only last a short time." | | > In fact, many EV batteries may outlast the vehicles they | are installed in, then enjoy a second life in a stationary | storage application before finally being recycled, | according to EVANNEX. "At the end of the vehicle's life -- | 15 or 20 years down the road -- you take the battery out of | the car and it's still healthy with perhaps 60 or 70% of | usable charge," Thomas said. | | > "It's more sustainable to take the battery pack out of | the car after 20 years, recycle the car, and reuse the | battery. By far the easiest thing to do is take the | complete battery out of the vehicle, put it in a shipping | container in a rack, and plug that into a solar farm." | | Can't speak to a Leaf, but I have fast DC charged my 2018 | Model S almost exclusively over the last 100k miles and its | pack has degraded only 6%. | galangalalgol wrote: | The leaf is notorious for fast degradation in hot | climates due to a poor cooling system. The model S, by | 2018 anyway, sets the bar for both thermal and charging | management. People outside of those climates mostly think | about cold being a temporary range reducer, but if 40c is | a normal or even cool summer day where you live, many EVs | are simply off the table due to battery life concerns. | The population of places with that sort of climate is | growing faster than the others, so it really is worth | addressing. | luhn wrote: | > many EVs are simply off the table due to battery life | concerns | | What EVs would be off the table? The Leaf is notably bad | in this regard, as you mention, because the battery is | passively cooled. However, all the other EVs I'm aware of | are actively cooled and should be fine in hot temps. | | It's an earnest question--I don't know anything except as | a consumer who's shopped around for an EV, and as a | resident of a hot climate I'd be interested in knowing | what I need to look out for. | galangalalgol wrote: | The spot checks I've done mostly show everything but | nissan and gm having active cooling beyond a fan. But | even within liquid cooling not all use the ac to keep the | pack below ambient temp nwhen it gets too hot. I think | kia and tesla are the only two I decided I was sure would | be ok. | mikestew wrote: | _" Almost all of the [EV] batteries we've ever made are | still in cars."_ | | That's because replacing the battery in a 2011 Nissan | Leaf will likely "total" the car (in that, the | replacement cost would be more than the car is worth). | It's the boat we're in now. Five, six, eight grand to | replace the battery for a car that even dealers are only | asking $7K for. Where are the cheap replacement batteries | that we were promised when we bought the car? My guess | is, "we'd rather place those batteries in $70K cars, so | those are the customers you're competing with for battery | supply." So that's how we're going to replace the | battery: with a new Hyundai IONIQ 5. | | _In fact, many EV batteries may outlast the vehicles | they are installed in, then enjoy a second life in a | stationary storage application before finally being | recycled, according to EVANNEX._ | | "May", or may not. We don't know, because despite the | chatter, I'm not seeing this secondary car battery use. | Probably because no one replaces the batteries, | because...it's not worth it. | | _Can't speak to a Leaf, but I have fast DC charged my | 2018 Model S..._ | | Your Tesla also has the advantage of seven years of | battery advancement over our Leaf, which has degraded | 25%. And the Leaf battery thermal management is non- | existent. OTOH, as my wife and I push up against | retirement age, with a liquid-cooled battery pack and the | 12 years of learning about battery management, I'm | assuming that the battery in the new Ioniq 5 coming this | week will outlive us. | Dylan16807 wrote: | > That's because replacing the battery in a 2011 Nissan | Leaf will likely "total" the car (in that, the | replacement cost would be more than the car is worth). | | Yeah, well, totalling shouldn't work like that. A car | with a new battery should be worth several thousand more, | and the totalling calculation for replacing the battery | should be based on the post-work value, not the pre-work | value. | belval wrote: | Yeah the Leaf ~2011 is infamous as an earlier "bad" | battery design so I wouldn't extrapolate too much from | it. The reality is also that as battery capacity | increases, people simply won't notice 10-15% degradation | of the pack because their commute is so much shorter than | the vehicule's range. | mikestew wrote: | And I'm not really extrapolating too much from it, as I | expect our soon-to-be-in-the-driveway Ioniq 5 to perform | much better (as in, outlives me). The Leaf was the first | mass-market electric car in, what, 100 years? Yeah, we | expected some early-adopter teething pains (including a | short-lived battery), and we have no complaints with the | OG Leaf, enough so that we swore off ICE vehicles years | ago and await our 2nd electric car. | | But at the same time, it's a counter to _Nissan marketing | guy_ trying to mansplain to me about their battery | lifecycle. I own one of your batteries, Marketing Guy, | and I 'm detecting slight hints of marketing bullshit. | neuronexmachina wrote: | Is there a consumer market yet for buying/selling old EV | batteries for stationary storage? Some quick googling | isn't turning anything up. | myself248 wrote: | Batteryhookup and Jag35 are hobbyist-friendly places | dealing in such things. Safety or documentation are very | much YOYOMF. | mardifoufs wrote: | I can vouch for battery hookup, they even sell new/never | used overstock sometimes. Pretty good way to build your | own battery back up system, which has helped me a lot | when we lost power here in quebec for 4 days last week. | outworlder wrote: | Probably not at scale due to all the different form | factors. There are plenty of hobbyists doing that, | however. | rootusrootus wrote: | You can buy old Tesla modules (typically from wrecked | cars) on eBay. Once in a while I see people on the RV | forums use them instead of LFP, though honestly I'd much | rather have LFP for RV or home energy storage than | regular lithium ion. | acyou wrote: | Yes, vehicle batteries and stationary storage are used in | much more "forgiving" environments than laptops and power | tools, when it comes to cell life. Lower power draw, better | battery management systems, less temperature fluctuation, | less physical impact. | | Battery production is still massively wasteful in terms of | partially finished or finished products that need to be | scrapped. The reason is that battery quality is _critical at | every level_. One tiny piece of iron embedded in one battery | out of a million can mean a catastrophic fire and tens of | millions in damages. If there is a systemic defect that | manifests during cell testing and is caught, the whole | production batch should be scrapped. Most of this scrap | happens before the batteries are shipped, and you never see | it, except in this too-honest article. You see how this plays | out in car fires, resulting from battery defects, resulting | in large recalls. | | Run into defects in semiconductor manufacturing, and scrap | cost is lower, and you don't have an obvious and direct link | between the defects and catastrophic failure modes. | | Keeping iron particles and manufacturing defects out of | batteries isn't a "solvable" problem. You try to minimize it | and catch it. Without technical breakthroughs and using | existing technologies, the higher the batteries' performance, | the less the margin for error. | | We don't have a good baseline cultural understanding for what | lithium-ion batteries are. In general, household batteries, | AAs, AAAs, car batteries use a water-based electrolyte. They | do not catch fire. Lithium-ion batteries use an organic | solvent as electrolyte and when punctured, dropped, or just | cycling in everyday use if defective, turn into red-hot self- | propelled blowtorches. | londons_explore wrote: | > stationary storage that will eventually EOL | | I suspect stationary storage will never EOL. Even after tens | of thousands of recharge cycles, the battery can still store | _some_ energy, perhaps just 10% of the design capacity, but | thats still worth something so it 's still worth running. | | The only time it is worth throwing out is if the land is | valuable and you need it for another project. | | This does depend on there not being much 'parasitic load' - | ie. fans and pumps which run 24x7 which cost money to run | even when they aren't really needed when the battery capacity | and charge/discharge speed is really low. | peer2pay wrote: | Eh not sure about this one. | | With SoH decreasing the internal resistance increases and | the battery inherently becomes a fire hazard. At some point | the energy required for cooling will not be justifiable and | the battery will have to be decommissioned. | londons_explore wrote: | As internal resistance rises, you just need to charge | slower... | | A battery that normally takes an hour to charge can | charge 10x slower and take 10 hours to charge, and still | be providing some useful value. (nearly everywhere will | have a day/night power price discrepancy, as well as a | weekday vs weekend discrepancy, and a hot/cold weather | discrepancy - so there are lots of timescales over which | money can be made) | iseanstevens wrote: | I think this is the state of the art at scale currently. | | I bet if you can execute better they would love to hire you! ;) | acyou wrote: | Yes, I think you're right that this is the state of the art | at scale. | | I wish the article went into a little more detail on the | extent of technical achievement that was reached in | commissioning this facility. Never mind the core process, can | only imagine the scale of the fire suppression system, dust | and fume management, etc. It really is impressive. They | should publish a video tour. | | I think that this recycling facility occupies a supply chain | niche in a larger system: Dispose of old battery cells and | preserve the rest of the materials as concentrated ores. The | existing cells cannot be safely warehoused as cells, due to | fire risk. The concentrated ores can be stored cheaply and | safely and will maintain a stable or increasing indexed | commodity value, proportionate to improvements in refining | processes. | | I just think that getting the cell cores out intact and | separate from the steel casings would be a great start for | the subsequent materials separation processes. Imagine if the | cathode and anode foils could be further separated at the | time of cell disassembly, and you would have a few material | streams that would be simpler to process downstream: steel | casings contaminated with powder and maybe a little aluminum | and copper, cathode foils with the bulk of the cathode | powders and close to zero iron, anode foils with the bulk of | the anode powders and close to zero iron, and mixed powder | flakes with close to zero iron. | | I guess it's about where you move cost and complexity. I view | the whole cell grinding as moving complexity downstream. Yes, | it may end up being the right thing to do, but that will | depend on future technological developments in metal | refining, hydrometallurgical separation, and other | techniques. | coryrc wrote: | Reduce, Reuse, Recycle | | You seem upset that "reuse" is a different word than "recycle". | acyou wrote: | We may or may not develop processes to efficiently recycle | the "black mass". For now, these processes do not exist. | | Battery recycling may go in a different direction than it's | currently heading. We may decide to focus on separating out | the most valuable of these elements, or only elements from | certain battery chemistries. We may even decide that it's not | feasible to chemically separate ground battery materials | containing iron, chromium, or other contaminants. | | In the short term, re-using lithium-ion cells is not | particularly feasible due to issues with cell safety and | handling. In my mind, re-use doesn't enter into the | conversation. If cells are being decommissioned, they would | ideally be at or near the end of their useful lives anyways. | For instance, if a vehicle was in a car accident, you would | never re-use the cells, due to concerns about acceleration | damage. | coryrc wrote: | Re-use is happening all over. Used Nissan Leaf cells sell | for almost new prices. I wish it wasn't true because I'd | like a few packs myself. | bromuro wrote: | Recycling causes harm for the environment. It's not a viable | solution in the middle terms. | jabart wrote: | How do you think they get it out of the ground with all the | other contaminants? I'm making an educated guess that a | recycling business has figured out how to make it economical at | scale. | acyou wrote: | For each element, I believe there is a combination of | electrolysis, electrowinning, leaching and other | hydrometallurgical and refining processes that is used to | refine from ore into a pure state. | | In the article, lithium is extracted from the recycled cell | materials. Relatively cheap lithium can be extracted because | it occupies position #3 in the periodic table and has very | different chemical properties than most of the other | elements. According to the article, the expensive elements, | occupying positions #24 through #30 in the periodic table, | are left together in the black mass and re-sold. | | Separating elements #24 through #30 is not yet easy and | economical. The central challenges are: A. The elements are | all adjacent to one another in the periodic table B. The | finished outputs must be extremely pure in order to be | suitable for use in battery materials C. Centuries of | advancement in mining, metallurgical and process research and | development focuses (mostly) on how to get (mostly) pure | elements from ores | | That's not to say we won't get there. I just think that | opening a cell grinding and breakdown facility isn't a | particularly large step in the right direction. I actually | think it may be a step in the wrong direction, and that cell | processing facilities should perhaps be focusing on | complexity at the cell disassembly level, processing | individual cells to mechanically separate elements, given | that cells enter recycling facilities as attached/assembled | but relatively nicely separated casings, cathode and anode | foils, and cathode and anode powders. | | If there are large subsequent advancements in chemical | refining processes for separating elements #24 through #30, | my above assessments will be proven wrong. | ZeroGravitas wrote: | You seem to be adding some details not in the article. Are you | familiar with them? | | > Currently, Ascend sells most of these substances to the | market; | | I took that line to mean they sell the recycled materials. You | seem to think they are storing them as a combined goop. | acyou wrote: | I do have a little familiarity with lithium-ion technologies, | but no direct insight into battery recycling. Please correct | me if I'm mistaken. | | I absolutely do think that "recycled" battery materials are | being stored as combined goop or "black mass"! For the | following reasons: 1. I'm not aware of a commodity spot price | for battery sludge/powder 2. I'm not aware of any cell | manufacturer using recycled materials in their cathode | materials 3. I'm not aware of any cell manufacturer or | recycler processing recycled battery sludge/powder and re- | selling cathode materials made from recycled materials 4. I | am well aware of the large technical and cost barrier to | processing and separating this "black mass": The chemical | elements occupy all of the positions from #24-#30 in the | periodic table, and existing processes to separate the | elements are expensive and resource-intensive. | | What I don't have insight into is: who is buying recycled | battery material mixtures? If they are available cheaply, we | could speculate on them and hold them, assuming that refining | processes will grow cheaper over time, and that the value of | the recycled material mixtures will increase. | ZeroGravitas wrote: | Their website seems to be claiming they have some secret | sauce: | | > Our advantage starts with a remarkable innovation: Other | processes leach metals out of spent battery materials, but | our patented Hydro-to-Cathode direct precursor synthesis | process leaches out impurities, keeping the valuable metals | in solution and eliminating multiple steps in the recycling | flow. | londons_explore wrote: | I think the 'grind it up and use chemistry to extract the | valuable bits' is the future of recycling. | | The reality is that lifespans of products is so long (eg. 30+ | years) that no recycling process wants to be built to fit | standard mechanical designs from 30 years ago... and 20 years | ago... and 10 years ago... Multiply by the number of different | designs from different companies and different countries (even | with regulation, it is unlikely we would get one global | mechanically recyclable design). | | If process chemists can't extract everything, then you plasma- | ionize what's left and now you just have plain old elements to | deal with. | acyou wrote: | Chromium, manganese, iron, cobalt, nickel, copper and zinc | are elements # 24, 25, 26, 27, 28, 29, 30. The processes to | separate them are currently resource-intensive and expensive. | They need to be separated by conventional smelting and | refining processes or hydro metallurgical processes, or some | combination. These processes need to do a great job of | purification for the materials to be battery grade. | | Plasma ionization, can it be cheap and scalable? | makerdiety wrote: | > I think the 'grind it up and use chemistry to extract the | valuable bits' is the future of recycling. [...] If process | chemists can't extract everything, then you plasma-ionize | what's left and now you just have plain old elements to deal | with. | | So high temperature applications which remove strong bonds | and create programmable ions can lead to atomic elements? | londons_explore wrote: | steel recycling has the same concern. | | Sure, you can rip apart a building and say "ooh, thats a nice | steel beam - we could reuse that for another building, or cut | it into sheets to roll flat into something else"... But it is | cheaper and easier just to chuck it into a furnace and melt | it down and start from scratch. | acyou wrote: | This is the correct way of thinking, and is widely | applicable to many commonly recycled materials. Wood, | aluminum, steel, and some plastics can be efficiently | processed in this way. | | Battery materials and applications are different. They | cannot be cheaply and easily melted down and re-used. The | main constituents are all very similar and difficult to | separate, and need to be separated extremely well in order | to be used in battery applications. | | The lithium carbonate extraction is very telling. Lithium | is #3 in the periodic table. The remaining elements that we | would want to extract occupy every number from #24 through | #30. The reason that they are extracting cheap lithium and | none of the heavy, expensive elements, is that more process | development needs to be done. | | In light of the above, creating a facility to grind up | batteries does not represent much progress towards the core | problem, and is not a particularly large step in the right | direction. It would be like making a facility to grind up | plastic, without having a process in place to recycle the | plastic. It's great, but you need more, much more. | jgtrosh wrote: | But that's not the same, the above process would be like | melting the steel and glass and concrete from the building | and hope future chemistry allows us to separate them | rimunroe wrote: | I'm not a chemist, but this is something we're already | very good at, and have been for quite some time. Silicon | oxides occur very commonly in iron ores, and are a major | component of slag. | WJW wrote: | Current chemistry allows us to do that just fine. Glass | melts at a much lower temperature and is much less dense | than steel. Concrete is not as dense as steel, but melts | at a much higher temperature. So, if you heat up the | whole mixture to steel melting temperatures, the glass | and steel will melt and can be poured off, while the | concrete will stay solid. Then the molten mixture of | steel and glass will naturally separate because the steel | part is so much heavier than the glass part and they | don't naturally mix all that well. | | (Fun fact, glass pane manufacturing is often done by | floating the molten glass on a bath of molten metal so | that the surface tension will make it flat. AFAIK they | don't usually use molten steel as the metal though.) | jopsen wrote: | But if you can pull out the steel beams without all the | concrete, melting it will be a lot cheaper. | | Imagine grinding up a bridge or tunnel and trying melt | all the steel out of the concrete. | | That sounds expensive. ___________________________________________________________________ (page generated 2023-04-10 23:00 UTC)