[HN Gopher] The biggest EV battery recycling plant in the US is ...
       ___________________________________________________________________
        
       The biggest EV battery recycling plant in the US is open for
       business
        
       Author : orangebanana1
       Score  : 332 points
       Date   : 2023-04-10 15:38 UTC (7 hours ago)
        
 (HTM) web link (www.canarymedia.com)
 (TXT) w3m dump (www.canarymedia.com)
        
       | atleastoptimal wrote:
       | The moment I read this headline I went straight to comments to
       | find the 20 people decisively declaring it completely useless.
       | Classic HN
        
         | HopenHeyHi wrote:
         | [flagged]
        
           | jamespo wrote:
           | Why should anyone spend their time trying to persuade a 20
           | day old account on here?
        
             | HopenHeyHi wrote:
             | Look at the numbers and think it through on your own, don't
             | need to persuade me or anybody of anything. You should do
             | that if you care whether or not the idea/numbers add up at
             | all for your own sake. Persuade yourself. As you care about
             | the truth.
             | 
             | Right?
             | 
             | ..
        
       | [deleted]
        
       | nicenewtemp84 wrote:
       | I wonder how they are able to shred batteries safely, but we hear
       | that an accident that leads to pack deformation can easily start
       | a massive fire.
        
       | vrglvrglvrgl wrote:
       | [dead]
        
       | Tagbert wrote:
       | There are other companies working on these processes.
       | 
       | US increases EV battery recycling capacity with new AL facility
       | processing up to 10K tonnes annually
       | https://electrek.co/2022/10/14/us-increases-ev-battery-recyc...
       | 
       | Redwood Materials recovers ~95% of metals from EOL battery packs
       | https://www.teslarati.com/redwood-materials-metal-recovery-e...
        
       | m463 wrote:
       | A lot of old ev batteries are snatched up by people who want to
       | use them in whole-house battery systems.
       | 
       | I wonder if recycling of ev batteries might be premature for some
       | or many cells?
        
         | jeffbee wrote:
         | A lot? I bet the number of EV battery packs that have been
         | turned into whole-house batteries by individual homeowners is
         | in the single digits and might be zero.
        
       | jaberabdullah wrote:
       | [flagged]
        
       | jaberabdullah wrote:
       | [flagged]
        
       | xeromal wrote:
       | Glad my homestate is making decent strides towards building new
       | things. We just had a nuclear reactor come online, a rivian EV
       | truck factory is here, and now this. We do a bunch of naughty
       | things but I can be proud of these at least.
        
         | cpursley wrote:
         | There's a bunch of new plants and factories going up in Georgia
         | (maybe there's a comprehensive list somewhere). Definitely
         | bodes well for Georgia's future in terms of economics.
        
           | xeromal wrote:
           | Yeah, the news is pretty non-stop of new things opening up.
           | Atlanta trying to become the new hollywood I think
           | kickstarted all this at least in my head timeline but I'm
           | sure some hardworking business owners and politicians really
           | just focused on bringing in new work.
        
             | blamazon wrote:
             | I think it goes a lot further back, one semi-serious data
             | point: the "Chamber of commerce runs Atlanta" meme was
             | satirized by the TV show Futurama in the year 2000:
             | 
             | https://en.wikipedia.org/wiki/The_Deep_South_(Futurama)
             | 
             | https://youtu.be/LeYihjMo0Bk
        
         | megraf wrote:
         | This is likely due to GA's extensive rail network[0].
         | 
         | [0] -
         | https://opendata.atlantaregional.com/datasets/GARC::railroad...
        
           | kfajdsl wrote:
           | Man, if only we could use some of that for passenger rail...
           | Being able to go from Atlanta to Savannah without a car would
           | be awesome.
        
             | Analemma_ wrote:
             | It's a nice idea but keep in mind that any freight which
             | gets displaced from rail thanks to passenger cars would
             | have to go by truck instead, probably with a massive
             | increase in net emissions. Having passengers and freight
             | share track in the US is probably not a win for the
             | environment; passengers would need separate track instead.
        
               | KennyBlanken wrote:
               | You have that backwards. Low occupancy vehicle travel is
               | the most wasteful form of personal transit.
               | 
               | Rail passengers displaced by freight become low occupancy
               | vehicle trips.
               | 
               | In my state, a commuter rail coach car has about 180
               | seats. Let's be cautious and assume 50% occupancy.
               | 
               | That's 90 people, and based off the US passenger car
               | fleet averaging 25mpg, they collectively would have used
               | 3.6 gallons of gas per mile.
               | 
               | An eighteen wheeler gets 5-10 miles per gallon.
               | 
               | Even assuming just 5mpg, the passengers in that one coach
               | car would have used _eighteen times more fuel_ than the
               | truck hauling a container would.
               | 
               | Furthermore: freight and passenger use of rail are not
               | mutually exclusive uses. Freight is in theory far less
               | sensitive to scheduling, and like a lot of trucked
               | freight, can happen during times passenger use is low.
               | But because industry has squeezed their supply chains to
               | the hair of breaking under "just in time delivery" to
               | minimize warehouse space and the like...which bit us
               | pretty severely in the pandemic...freight companies are
               | optimizing for shareholder profits and own the tracks. So
               | they prioritize their freight over passengers. Result?
               | Passenger service is riddled with service issues, leading
               | to less passenger use, which is fine as far as the
               | freight companies are concerned, because they can move
               | more freight.
               | 
               | The core problem is that critical infrastructure is being
               | run privately by for-profit publicly traded companies.
        
               | TYPE_FASTER wrote:
               | Adding passenger traffic does not necessarily require
               | displacing freight traffic.
               | 
               | Here's a document that contains a map of current rail
               | density: https://www.dot.ga.gov/InvestSmart/Freight/Georg
               | iaFreight/Ta...
        
               | elif wrote:
               | But things like "okay now wait on this random section of
               | tracks for 3 hours because of a pass and traffic down
               | stream" are routine on freight lines, but obviously not
               | desirable for passenger rail.
        
               | babypuncher wrote:
               | So you build more rail
        
               | JumpCrisscross wrote:
               | > _build more rail_
               | 
               | Passenger rail doesn't tend to break even on long-
               | distance dedicated routes, even taking into account
               | externalities.
        
               | bluGill wrote:
               | But it does very well at medium distances while you find
               | all over.
        
               | JumpCrisscross wrote:
               | > _it does very well at medium distances_
               | 
               | Depending on density. I'd wager the Atlanta metropolitan
               | area is just about crossing that threshold, _i.e._ they
               | should built it now.
        
               | danielvf wrote:
               | Atlanta does have trains, and in fact has the 8th most
               | annual riders of any US city, right behind the Bay Area.
               | 
               | https://en.wikipedia.org/wiki/MARTA_rail
        
               | JumpCrisscross wrote:
               | I guess MARTA is between municipal and regional rail,
               | sort of like BART. I meant for connecting the Atlanta
               | metropolitan area to its region, not intraconnecting.
        
               | elif wrote:
               | 91,000 daily riders according to that link
               | 
               | 2,000,000 daily vehicles on this Atlanta transit system
               | 
               | https://en.m.wikipedia.org/wiki/Interstate_285_(Georgia)
        
               | bluGill wrote:
               | Roughly speaking the density of the US east of the
               | Mississipi and the far west coast is dense enough. The
               | rocky mountains and Alaska really bring our average
               | density down.
        
               | grogenaut wrote:
               | In like 1/3rd or less of the land mass of the us yes.
        
               | iknowstuff wrote:
               | It doesn't have to. How much do our freeways cost us? esp
               | with externalities?
        
               | waterheater wrote:
               | >How much do our freeways cost us? esp with
               | externalities?
               | 
               | Rail also has cost, including externalities. For example,
               | as a wise person on the Internet once said, "Trains take
               | you from a place you don't live to a place you're not
               | going to." The "last-mile problem" is a non-trivial
               | factor to building train networks which by definition is
               | not solvable by more rail.
               | 
               | You're considering a cost analysis. A more complete
               | analysis is the benefit-cost analysis (BCA). If the
               | benefits outweigh the costs, the project is a net
               | positive for society. Asking only how much our freeways
               | cost us avoids consideration of the known benefits.
               | Here's a BCA from 2021 which investigates a highway
               | project, so you can see exactly how much freeways benefit
               | and cost us:
               | https://www.mdot.maryland.gov/OPCP/I-81BCA_Report.pdf
               | 
               | >It doesn't have to.
               | 
               | That's a nice sentiment, but sometimes the energy
               | required to reform is higher than expected losses. The
               | entire Amtrak network is kept afloat because of a handful
               | of lines in New England between DC, New York, and Boston.
               | Amtrak basically runs a loss everywhere else.
        
               | mschuster91 wrote:
               | > The "last-mile problem" is a non-trivial factor to
               | building train networks which by definition is not
               | solvable by more rail.
               | 
               | The trivial answer is to build out last-mile services:
               | trams, buses, actually usable bike lanes, and something
               | that could perfectly well work in US suburbia hell (wide,
               | but barely frequented streets): automated "people
               | movers".
        
               | waterheater wrote:
               | You say last-mile services are trivial, but they
               | absolutely are not trivial in the slightest, and assuming
               | they are demonstrates a fundamental lack of understanding
               | of how change gets made in a democratic, even republican,
               | manner.
               | 
               | Changing the primary transportation mode of a population
               | requires a cultural shift to adopt the new mode. The
               | population must be willing to forgo what they already
               | have in favor of something new. You are saying that
               | automated "people movers" (which is an emotional sketch
               | rather than an defined policy item) will work well in
               | car-ubiquitous US suburbia, but these folks live in
               | suburbia specifically because of low population density
               | and general quality-of-life. They explicitly enjoy being
               | around people they know and not being around people they
               | don't know. Any solution you're proposing must respect
               | their existing values while providing an alternative
               | option.
               | 
               | Your examples of last-mile services aren't really last-
               | mile services, save for the final one:
               | 
               | >trams
               | 
               | Since it seems infeasible to allow anyone to board a tram
               | at any point on its journey, tram stops will be
               | necessary. Perhaps you now face a last-quarter-mile
               | problem, which is better but still may not be good enough
               | for that specific population. Track maintenance may be
               | significantly lessened by using a "trackless tram", but
               | such would have severe challenges in a snowy climate.
               | Trams only work in dense urban environments.
               | 
               | >buses
               | 
               | Buses have been used in cities for many decades, so our
               | understanding of them is that they work generally well.
               | Buses are common in suburban environments with many low-
               | income residents. The benefit of buses is their limited
               | amount of supporting infrastructure and route
               | adaptability. However, similar to the tram situation, a
               | bus still does not get you directly to your home.
               | 
               | >actually usable bike lanes
               | 
               | Bike lanes in dense urban environments are almost always
               | a net positive. What constitutes an "actually usable"
               | bike lane depends on an individual's risk tolerance. As a
               | last-mile problem, not all people are physically able to
               | bike from a train station, though ebikes do help. Again,
               | weather can impact people being willing to bike, let
               | alone leave the house.
               | 
               | >automated "people movers"
               | 
               | This service is more conceptual, but I imagine you're
               | thinking of a Waymo-style service, where you can summon
               | an autonomous vehicle which will pick you up at home and
               | take you to-and-from the station. The main issues here
               | are availability and reliability. If addressed, you'll
               | likely crack the suburban transportation nut, but such
               | individualized transportation in cities isn't
               | sustainable.
        
               | babypuncher wrote:
               | > Trains take you from a place you don't live to a place
               | you're not going to.
               | 
               | Airplanes have the exact same problem, but I don't see
               | people saying we should stop investing in airports.
               | 
               | For long distance travel, I don't think it's a huge
               | problem that you might need multiple modes of transit to
               | get all the way from A to B.
        
               | bluGill wrote:
               | Trains are too slow for long distance travel. They are
               | useful for short and medium distance travel, but for such
               | trips travel time to the station becomes more important.
               | If this isn't made convenient people will quickly decide
               | their car is better: it goes when they want to go, and
               | goes directly to where they want to be.
        
               | TylerE wrote:
               | Different model. Planes have much greater network
               | effects. Consider a trip between New York and Dallas. A
               | plane can fly a direct route, and will if there is much
               | demand.
               | 
               | A train system can't do that... in my example you'll end
               | up either going South along the coast and then west
               | through New Orleans to San Antonio, and then back north
               | to Dallas, or the same but reach Mew Orleans via Chicago.
               | 
               | Trains work well when there is a large central(ish) city
               | that can act as a hub? Like London, Paris, or Berlin. Not
               | so well in the US where the population is heavily biased
               | towards the outer rim, with a relatively a gaunt desert
               | of nothing in the middle.
        
               | waterheater wrote:
               | >Airplanes have the exact same problem, but I don't see
               | people saying we should stop investing in airports.
               | 
               | Fair point. We should then see if air travel holds a key
               | advantage over rail travel in the USA. As I see it, the
               | answer is in both space and time savings, both of which
               | minimize cost and maximize benefit. The time savings are
               | particularly pronounced, especially over distances
               | greater than, say, a few hundred miles. Happy to
               | elaborate on the savings in more detail, if you desire
               | such.
               | 
               | >For long distance travel, I don't think it's a huge
               | problem that you might need multiple modes of transit to
               | get all the way from A to B.
               | 
               | That is, of course, your opinion. I'm sure there are
               | tens, if not hundreds, of millions of Americans who will
               | strongly disagree with you because they are, in no
               | particular order: feeble, disabled, terrified of a
               | particular mode of transit, hurried, cost-conscious,
               | traveling with multiple young children, etc.
        
               | cyberax wrote:
               | Freeways are amazingly cheap. 1 mile of new 6-lane
               | freeway on level terrain is about 3 million:
               | https://www.strongtowns.org/journal/2020/1/27/how-much-
               | does-...
               | 
               | Amazingly, railroads are not much cheaper. The current
               | costs of tracks are estimated at about $2 million per
               | mile, and this is without taking into account all other
               | necessary rail infrastructure (such as sorting yards,
               | maintenance facilities, etc.).
               | 
               | And CO2 emissions are being fixed by switching from gas
               | cars to EVs.
        
               | adgjlsfhk1 wrote:
               | The problem is that 1 mile of rail can move a lot more
               | passengers than 1 mile of road.
        
               | cyberax wrote:
               | The calculations on that page are not correct. First, the
               | average car occupancy is not 1, it's 1.5 on average.
               | Second, the lane capacity is 1900 cars per hour (that's
               | maximum at around 45 mph, btw). So this works out to 8550
               | people per hour.
               | 
               | A realistic scenario for commuter trains (that would
               | replace a freeway) is 1 train every 10 minutes, and even
               | this is pretty tough. So you have 6 trains per hour, and
               | to match the throughput you'd need 1425 people per train.
               | 
               | Most train platforms are maxed out at well below 10 cars
               | (Caltrain is 6 cars), 20 car trains are just pure
               | nonsense for commuting. So for 10 car trains it'll be
               | around 150 people per car. Caltrain cars are 130 seats
               | per car ( https://www.greencaltrain.com/2014/05/keeping-
               | up-with-caltra... ), with another 40 standing places.
               | 
               | Basically, a perfectly run commuter train system is
               | _just_ barely comparable with a regular 6-lane freeway.
               | 
               | Sorry train fans, but trains are not that great for
               | commuting.
        
               | judge2020 wrote:
               | Correction, trains specifically. Subways and light rail
               | are immensely higher ROI (as in, benefit vs cost) within
               | a city since it effectively forces people close together,
               | while a 6-lane-on-each-side highway isn't economically
               | feasible for all of the high-traffic areas.
        
               | ProfessorLayton wrote:
               | BART has a capacity of 200 passengers per car in their
               | legacy fleet, 241-256 for their new fleet, and regularly
               | has 10 cars per train during peak hours [1] and travels
               | 80mph.
               | 
               | [1] https://wbcapp.oaklandnet.com/cs/groups/public/docume
               | nts/pro...
        
               | richardw wrote:
               | > Sorry train fans, but trains are not that great for
               | commuting.
               | 
               | Quick comparison: more people (3.6m) go through Shinjuku
               | Station in Tokyo than the daytime population of
               | Manhattan, at 3.1m. Only half of those travel into
               | Manhattan, using all modes of transport. When things get
               | extreme it's hard to just double the road network and
               | parking into a single location.
               | 
               | https://en.m.wikipedia.org/wiki/Shinjuku_Station
        
               | sixstringtheory wrote:
               | What is the route capacity for a lane of freeway vs a
               | rail line? I assumed it's the opposite, since a freeway
               | has continuous throughout while a rail line is discrete,
               | but I don't have a good intuition for comparing the scale
               | of each mode.
        
               | dragonwriter wrote:
               | > What is the route capacity for a lane of freeway vs a
               | rail line? I assumed it's the opposite, since a freeway
               | has continuous throughout while a rail line is discrete
               | 
               | According to this book (which provides assumptions and
               | calculations supporting) [0], 10:1 in favor of rail, as a
               | conservative estimate.
               | 
               | https://eng.libretexts.org/Bookshelves/Industrial_and_Sys
               | tem....
        
               | cyberax wrote:
               | > A rush-hour train may consist of 20 cars
               | 
               | The author is smoking some hard crack.
        
               | AnimalMuppet wrote:
               | Well, BART has no problem running 9-car trains. I don't
               | know if that's rush hour or not, but I've seen them. If
               | the rest of the math is right, that still gets you
               | 4.5-to-1 in favor of rail.
        
               | bluGill wrote:
               | How do you calculate capacity? Safety engineers keep
               | yelling that drivers need to keep 3 seconds between cars,
               | but in reality they most drive about .3 seconds from the
               | car in front. There is nearly a 10x difference in freeway
               | capacity between just those two.
               | 
               | Trains tend to maintain longer distances, but if you want
               | to ignore safety we can follow a lot closer.
        
               | ClumsyPilot wrote:
               | > And CO2 emissions are being fixed by switching from gas
               | cars to EVs.
               | 
               | Not reall, rail is 9 times more energy efficient than
               | road vechicles. Thats why its cheaper to have a diesel
               | locomotove move freight than to pour the same diesel into
               | trucks.
               | 
               | The whole reason rail exists is thsa its the most
               | efficient form of tranportation on land.
        
               | bluGill wrote:
               | There are a lot of assumptions in the idea that trains
               | are more efficient than road vehicles. Trains tend to
               | carry more heavy bulk goods like coal, if they had more
               | light things the numbers would change. Trains get a lot
               | of efficiency from running very long trains, but that
               | only works out when you have a lot of things going the
               | same way, if you had smaller trains from each warehouse
               | (which now is done by truck) that would reduce th
               | efficiency.
               | 
               | Yes trains have some efficiency advantages, but in
               | similar service the difference is small. You only get
               | those advantages when you use trains for things that
               | trucks cannot do at all.
        
               | mikepurvis wrote:
               | The very long trains of mostly goods like coal are not an
               | inevitability, though-- it's a result of rail companies
               | implementing PSR in response to some pretty specific
               | incentives, see:
               | 
               | https://www.nytimes.com/2022/10/09/opinion/business-
               | economic...
               | 
               | A number of YouTube video essays argue the sides of this
               | as well, here's one based around Sen. Sanders confronting
               | a rail CEO in the wake of the recent Ohio derailment:
               | https://youtu.be/e4w0q5NzCwA
        
               | babypuncher wrote:
               | You're comparing dollars-per-mile of infrastructure when
               | the more important metric is dollars-per-passenger-mile.
               | You can build 1 mile of freeway for not much more than 1
               | mile of rail, but that mile of rail can serve
               | considerably more passengers.
        
               | mikepurvis wrote:
               | Two other factors that aren't coming up in this analysis
               | are long term maintenance costs (highways in Ontario are
               | constantly being resurfaced) and land use opportunity
               | costs (it's simply not viable to run six lanes of freeway
               | into most CBDs, and doing it with grade separation leads
               | to raised highway eyesores or insanity like Boston's Big
               | Dig).
               | 
               | In any case, as others have pointed out, we don't have to
               | argue hypotheticals here-- China, Japan, France, Germany,
               | etc have all shown that frequent-service electrified
               | passenger rail is perfectly possible and an incredible
               | public good.
        
             | samstave wrote:
             | Yah, but youre still in gorgia
        
           | xeromal wrote:
           | I grew up near one of those major lines, the one that goes
           | along 515. We used to try to get a train to flatten a penny
           | for us or race it on our fourwheelers. Never got a flattened
           | penny though. lol
        
             | bluGill wrote:
             | I used to get lots of flattened pennies. The trains throw
             | them so you have to spend a lot of time searching the
             | gravel around the tracks. Be sure to watch for other trains
             | so you don't get hit.
        
             | redundantly wrote:
             | Gotta tape the coin to the track so it doesn't rattle off
             | before the train gets to it, or use chewing gum.
        
               | xeromal wrote:
               | I was around 5 years old so my logic was pretty simple. I
               | think I tried a heavy rock lol
        
       | jeffrallen wrote:
       | Where the heck are they going to find feedstock? Renault found
       | that the batteries don't wear out, they just keep running, going
       | on 10 years.
        
         | to11mtm wrote:
         | I'm guessing at least some consumer batteries (i.e.
         | laptop/phone/ebike/etc) can also be recycled at the same
         | facilities; These are often of similar chemistry but may have
         | lower lifespans and there would be no reason the facility could
         | not process them. [0]
         | 
         | [0] - A good example would be 18650 batteries; these are used
         | by Tesla but are found in lots of other things.
        
         | Ensorceled wrote:
         | I suspect, eventually mostly insurance writeoffs, wrecks etc.
        
         | mardifoufs wrote:
         | I guess the Nissan Leaf might single handedly provide for
         | enough initial feedstock, considering how quickly their
         | batteries degrade. Just awful battery management from Nissan on
         | that car.
        
       | foolfoolz wrote:
       | given the u. s. goals of evs and energy storage recycling
       | batteries domestically instead of shipping the metals off to
       | cheaper destinations is going to become a matter of national
       | security as we won't produce enough metals on our own
        
         | pkaye wrote:
         | The infrastructure bill had funding for domestic extraction and
         | processing of critical minerals. Also US has been encouraging
         | Canada to do the same including providing some grants to
         | Canadian companies to get started. Below is the list of
         | minerals.
         | 
         | https://www.usgs.gov/news/national-news-release/us-geologica...
        
       | legitster wrote:
       | Super cool development. Love seeing people actually acting on the
       | laws of of supply and demand.
       | 
       | > The scrap and used batteries go through mechanical shredding
       | and sieving, which produces "black mass." Ascend extracts lithium
       | carbonate from the mass; the remaining mass contains materials
       | such as graphite, nickel, cobalt and manganese.
       | 
       | The article brags about the input, but is cagey on the details of
       | the about. Of the 30k tons processed in a year, what percentage
       | is reconstituted?
        
       | JumpCrisscross wrote:
       | We have a dearth of battery-grade metals refining in America.
       | Battery plants need specialised powders to do their work. Making
       | them isn't easy.
       | 
       | Many aspiring refiners brand themselves as recyclers, since
       | turning metals and old batteries into battery-grade powder is
       | more similar than one would expect. (Lithium carbonate.)
        
         | Vt71fcAqt7 wrote:
         | That's interesting. Can you expound on this?
        
           | JumpCrisscross wrote:
           | > _Can you expound on this?_
           | 
           | Which part?
        
             | Vt71fcAqt7 wrote:
             | >turning metals and old batteries into battery-grade powder
             | is more similar than one would expect.
        
               | bluGill wrote:
               | I'm not really an expert, but one obvious thing is you
               | need to take non-pure metals and purify them. Recyclable
               | batteries fail when the chemicals instead chemically
               | combine with something other what you intend them to,
               | crystalize, or otherwise become not the pure metal you
               | start with. That impure metal is not conceptually
               | different from ore, and the same process to turn ore into
               | battery material must be done.
               | 
               | Note that ore is more complex as you need to remove a lot
               | more non-battery stuff, while in a used battery what you
               | want is still in fairly high concentration, just not in
               | the form a battery needs.
        
               | samstave wrote:
               | As an ignoramous ; what is it about Lithium specificall
               | that makes it special to batteries?
               | 
               | Is is that it freely ejects electrons at a higher rate
               | than other materials, given a certain catalyst?
        
               | bluGill wrote:
               | That was covered in my college chemistry class, but I
               | took it 25 years ago and don't really remember the
               | details. Electro negativity comes to mind, but I might
               | have the terms wrong. In any case the laws of chemistry
               | apply.
        
               | sethhochberg wrote:
               | Generally yeah - it is both willing to give up and take
               | back electrons pretty easily (so, discharging and
               | charging) but in the modern era another really important
               | factor is that it balances having these properties and
               | also being very light relative to the amount of energy it
               | can hold in a battery. Good for portable applications
               | like cell phones, cars, etc.
        
               | [deleted]
        
               | Scoundreller wrote:
               | Lithium is at the top, so you get the most voltage per
               | molecule.
               | 
               | Then there's other factors like discharge recharge,
               | temperatures, all that, but lithium is basically the best
               | if you can get the other factors to play nice too:
               | 
               | http://hyperphysics.phy-
               | astr.gsu.edu/hbase/Tables/electpot.h...
        
               | JumpCrisscross wrote:
               | Recycling batteries involves shredding them into black
               | mass [1] and then extracting lithium carbonate from it.
               | This is the same stuff lithium from mines and brine
               | fields is processed into [2]. (Carbonate is processed
               | into lithium hydroxide [3], the stuff we trade [4] and
               | mix in batteries.)
               | 
               | In summary, they all start with pulverized stuff from
               | which lithium carbonate is extracted and turned into
               | lithium hydroxide. The fact that it's batteries versus
               | rock just changes the front end; nothing downstream could
               | care less.
               | 
               | [1] https://catalysts.basf.com/blog/lets-talk-recycling-
               | what-is-...
               | 
               | [2] https://samcotech.com/what-is-lithium-extraction-and-
               | how-doe...
               | 
               | [3] https://en.wikipedia.org/wiki/Lithium_hydroxide
               | 
               | [4] https://www.cmegroup.com/markets/metals/battery-
               | metals/lithi...
        
               | Waterluvian wrote:
               | Hmmm so they don't really disassemble the batteries. They
               | just grind them all up and then use physical and chemical
               | processes to filter the bits they want?
               | 
               | I guess this makes sense at scale. I'm not sure what I
               | was picturing.
        
               | nine_k wrote:
               | I suppose they disassemble large racks of batteries, to
               | remove the strong structural metal which us hard to
               | shred, and maybe copper wires that are expensive. But not
               | farther.
               | 
               | Individual cells are shredded, the cover metal is removed
               | by magnets, anything soluble is removed by water or other
               | solvents, whatever remains possibly may be further
               | processed, or can go safely to a landfill.
        
               | ClumsyPilot wrote:
               | Generally, all forms of recycling that reauire manual
               | dis-assebly don't really work. Labour cost is too much.
               | Broken and damaged items dont dissasemble. each itme is
               | unique, that sort of thing. Thats why plastic recycling
               | and electribics recycling doesn't work.
               | 
               | Recycling of metals and glass succeedd because you can
               | just grind and melt everything.
        
               | Waterluvian wrote:
               | So when I'm asked to obsessively clean out my aluminum
               | recycling, I've always assumed that's just a favour to
               | their equipment. But surely the process expects FOD and
               | messy cans.
        
               | maxerickson wrote:
               | It's staged and transported. So like the less food there
               | is at the collection site the less stink and rodents
               | there will be.
        
               | yurishimo wrote:
               | I've always wondered this. In my small town in The
               | Netherlands, plastic and metal go in the same recycling
               | sack. They specifically state that you don't need to
               | obsessively clean the containers, but they should be
               | "empty". I'm sure I've accidentally tossed some paper in
               | there, but I assume that gets burned away at some point.
               | 
               | But how they sort it afterwards? I have no idea. Not all
               | metal is conductive, though I have to assume they do some
               | magnetized sorting. Plastic can probably be blown away
               | for sorting further down the line.
               | 
               | Might need to explore this more in the near future!
        
               | Scoundreller wrote:
               | My thought was the melting process burns most of it off
               | and then the ash gets skimmed off the top.
               | 
               | not worth it to clean yourself.
        
               | dlkasajiewo wrote:
               | Nooooo! you can't use wikipedia as a source it's not
               | reliable >:(
               | 
               | jkjk. Thanks for sharing!
        
       | boshomi wrote:
       | Shanghai Metal Market lists used Lithium-ion battery
       | material/battery scrap
       | 
       | https://www.metal.com/price/New%20Energy/Used-Lithium-ion-Ba...
       | 
       | About 95% of Lithium can be reused.
        
         | KennyBlanken wrote:
         | Adding to this, a reminder that lithium ion batteries contain
         | very little lithium, and it's not elemental - an extremely
         | common misconception leading to people thinking that they can't
         | use water to stop a pack undergoing thermal runaway / on fire -
         | something that can _only_ be stopped via the cooling effect of
         | water.
        
           | samstave wrote:
           | So aside from the lithium, what is causing the runaway
           | thermal to fire/explosion??
        
             | [deleted]
        
             | rootusrootus wrote:
             | The electrolyte is very flammable and a short circuit
             | provides the temperature to ignite it. Some lithium battery
             | chemistries (LFP is probably the most common, but LTO as
             | well) are much less likely to burn when they fail
             | catastrophically.
        
             | boshomi wrote:
             | Nickel and Cobalt. This metal oxids creates molecular
             | oxigen.
             | 
             | This oxygen feeds the fire and make it hard to fight.
             | 
             | Lithium iron phosphate do not show this kind of reaction.
        
               | peteey wrote:
               | Yes and no. Lithium metal is the highly reactive element
               | in batteries.
               | 
               | Similar to Hydrogen and Sodium, elements in the first
               | column of the periodic table are highly reactive
               | (flammable) because they readily give away their single
               | electron in the outermost orbital.
               | 
               | Some Lithium battery variants might have marginally safer
               | properties, but they are fundamentally volatile at full
               | charge.
        
               | philipkglass wrote:
               | Commercial lithium ion batteries do not contain metallic
               | lithium in the charged or uncharged state. They have
               | lithium ions intercalated into the anode material in the
               | charged state.
               | 
               | Primary (disposable) lithium batteries do contain
               | metallic lithium in the charged state, and there are
               | efforts to develop rechargeable batteries using pure
               | lithium metal at the anode. Rechargeable batteries that
               | contain metallic lithium anodes would be able to store
               | more energy, but they are also more hazardous and
               | currently have low cycle life.
        
       | decide1000 wrote:
       | Is this different from how they recycle EV batteries in Europe?
        
       | ChancyChance wrote:
       | How many EV batteries are decommissioned each year, i.e., could
       | be recycled? This company can handle 70,000 per year according to
       | the article, but what is that number out of?
       | 
       | Side note about consumer lithium batteries: The nearest lithium
       | recycling near me is 40 miles away, and it costs $$ to drop of
       | your stuff. I can afford that, but I doubt most Americans
       | properly dispose of their batteries. Heck, I have a neighbor who
       | burns his trash near the road and one time saw him burning a few
       | car batteries in the pile.
        
         | theshrike79 wrote:
         | Not many. Not including a few larger recalls (Hyundai Kona for
         | example), the battery replacement percentage for EVs is under
         | 5%. The rest are still running on the original battery.[0]
         | 
         | This is the biggest limit for re-using and recycling EV
         | batteries, the damn things just won't die.
         | 
         | [0] https://www.businessinsider.com/electric-car-battery-
         | models-...
        
         | elihu wrote:
         | From the article, they actually get most of their waste
         | material from battery factories, which is interesting.
         | 
         | > "That's not to say there are enough old batteries coming in
         | to fill the factory. Currently, 80 to 90 percent of what's
         | going into Ascend's Covington facility is scrap materials from
         | battery factories, including SK Battery America's plant in
         | Commerce, Georgia."
         | 
         | Eventually we'll have a lot more end-of-life batteries, but for
         | now most of the EV battery packs that have ever been made are
         | still in the middle of their respective bathtub curves.
        
       | acyou wrote:
       | Pretty pathetic "recycling": 1. 80-90% of input is not even
       | batteries, it's scrap from woefully inefficient and low yield
       | battery cell manufacturing 2. "Recycling" consists of mechanical
       | shredding to combine all of the copper, aluminum, steel, cathode
       | materials, anode materials 3. A single extraction process pulls
       | out lithium carbonate, the rest is saved for the future as "black
       | mass" for as yet nonexistent processes to pull out the valuable
       | cobalt, nickel, manganese, phosphorus, graphite.
       | 
       | The approach taken is practical, but kind of stupid. We want to
       | physically separate these materials, so let's grind them into a
       | well mixed aqueous slurry, then let the process chemists loose to
       | solve it with science.
       | 
       | Particulate contamination of new or recycled battery materials
       | with iron particles is a particular concern. Grinding the steel
       | battery casings will not help.
       | 
       | The failure isn't with the battery recyclers, we shouldn't blame
       | them. The issue is that consumers pay $0.05 per cell to recycle
       | cells which at the moment are not recyclable, and we all see it
       | as OK. I got my Tesla, ... you. So, as a result, there is zero
       | incentive to consider the full product life cycle when designing
       | cells.
        
         | toomuchtodo wrote:
         | Input volume is low because vehicle batteries last forever.
         | Importantly, we can ramp on QA rejects, salavaged vehicles, etc
         | before there are tens of millions of EVs out there (not to
         | mention stationary storage that will eventually EOL) needing
         | waste management. Slow is smooth, smooth is fast.
         | 
         | https://cleantechnica.com/2022/09/21/surprise-nissan-leaf-ba...
         | 
         | Not super familiar with Ascend ground truth, but very familiar
         | with Redwood Materials state of the art.
        
           | mikestew wrote:
           | _Input volume is low because vehicle batteries last forever._
           | 
           | I am not sure of your meaning. Because, taken literally, our
           | 2011 Nissan Leaf would like a word with you.
        
             | kccqzy wrote:
             | I'm guessing the battery in your Nissan Leaf only has maybe
             | 60% of its capacity when new? That's not so bad that a
             | battery would be deemed unusable. If you didn't want that
             | battery, that battery probably would not end up in a
             | recycling site but reused in other low energy-density use
             | cases.
        
             | greenthrow wrote:
             | My 2014 Nissan Leaf still had great battery life when we
             | finally traded it in last year.
             | 
             | Often times a Leaf's entire pack can substantially recover
             | capacity by replacing a single problematic cell.
        
             | r00fus wrote:
             | Nissan for whatever reason never chose to do (and still
             | doesn't do in 2023) active battery thermal management that
             | every other EV manufacturer does - I have a Ford Focus EV
             | (2017) and despite being a complete econobox compliance
             | vehicle (which I still love) it actively manages battery
             | heat.
             | 
             | Luckily Leafs are a minority of all EVs so the point still
             | stands - EV batteries will likely outlive the car.
        
             | nkingsy wrote:
             | OG leaf battery design was legitimately flawed.
             | 
             | I had one for a while and watched the range drop from 50-40
             | "miles" (half that really) over less than 10k miles of
             | usage before I sold it.
        
             | nicenewtemp84 wrote:
             | Chevy Volt batteries are holding up great even in 2012
             | models. There are definitely people experiencing failures
             | of a cell leading to bricking the car, or even a temp
             | sensor failure in the pack leading to the vehicle bricking
             | itself, but for 95%+ of people it seems like a decade old
             | battery is doing great. I've got 170k miles on my decade
             | old Volt and everything seems good as new for now.
        
             | rootusrootus wrote:
             | I figure that over 10 years later, the fact that the only
             | example that consistently comes up is the Nissan Leaf means
             | we've made excellent progress on EV batteries. It's the
             | exception proving the rule.
        
             | outworlder wrote:
             | > Because, taken literally, our 2011 Nissan Leaf would like
             | a word with you.
             | 
             | 2011 was a particularly bad year for the Leaf. And they
             | were not great (battery life-wise) before 2015 ('lizard
             | pack').
             | 
             | The newer ones are faring much better. Sure, this is of no
             | consolation for your Leaf, but I'd keep an eye for a
             | battery pack from a Leaf that's totaled for other reasons
             | (minor accident causing airbag deployment, for example).
             | You can even add a larger battery than the one your model
             | came with.
        
             | toomuchtodo wrote:
             | > Many will be amazed to learn that Nic Thomas, Nissan's
             | marketing director for the UK, told Forbes recently,
             | "Almost all of the [EV] batteries we've ever made are still
             | in cars, and we've been selling electric cars for 12 years.
             | We haven't got a great big stock of batteries that we can
             | convert into something else," he added. "It's the complete
             | opposite of what people feared when we first launched EVs
             | -- that the batteries would only last a short time."
             | 
             | > In fact, many EV batteries may outlast the vehicles they
             | are installed in, then enjoy a second life in a stationary
             | storage application before finally being recycled,
             | according to EVANNEX. "At the end of the vehicle's life --
             | 15 or 20 years down the road -- you take the battery out of
             | the car and it's still healthy with perhaps 60 or 70% of
             | usable charge," Thomas said.
             | 
             | > "It's more sustainable to take the battery pack out of
             | the car after 20 years, recycle the car, and reuse the
             | battery. By far the easiest thing to do is take the
             | complete battery out of the vehicle, put it in a shipping
             | container in a rack, and plug that into a solar farm."
             | 
             | Can't speak to a Leaf, but I have fast DC charged my 2018
             | Model S almost exclusively over the last 100k miles and its
             | pack has degraded only 6%.
        
               | galangalalgol wrote:
               | The leaf is notorious for fast degradation in hot
               | climates due to a poor cooling system. The model S, by
               | 2018 anyway, sets the bar for both thermal and charging
               | management. People outside of those climates mostly think
               | about cold being a temporary range reducer, but if 40c is
               | a normal or even cool summer day where you live, many EVs
               | are simply off the table due to battery life concerns.
               | The population of places with that sort of climate is
               | growing faster than the others, so it really is worth
               | addressing.
        
               | luhn wrote:
               | > many EVs are simply off the table due to battery life
               | concerns
               | 
               | What EVs would be off the table? The Leaf is notably bad
               | in this regard, as you mention, because the battery is
               | passively cooled. However, all the other EVs I'm aware of
               | are actively cooled and should be fine in hot temps.
               | 
               | It's an earnest question--I don't know anything except as
               | a consumer who's shopped around for an EV, and as a
               | resident of a hot climate I'd be interested in knowing
               | what I need to look out for.
        
               | galangalalgol wrote:
               | The spot checks I've done mostly show everything but
               | nissan and gm having active cooling beyond a fan. But
               | even within liquid cooling not all use the ac to keep the
               | pack below ambient temp nwhen it gets too hot. I think
               | kia and tesla are the only two I decided I was sure would
               | be ok.
        
               | mikestew wrote:
               | _" Almost all of the [EV] batteries we've ever made are
               | still in cars."_
               | 
               | That's because replacing the battery in a 2011 Nissan
               | Leaf will likely "total" the car (in that, the
               | replacement cost would be more than the car is worth).
               | It's the boat we're in now. Five, six, eight grand to
               | replace the battery for a car that even dealers are only
               | asking $7K for. Where are the cheap replacement batteries
               | that we were promised when we bought the car? My guess
               | is, "we'd rather place those batteries in $70K cars, so
               | those are the customers you're competing with for battery
               | supply." So that's how we're going to replace the
               | battery: with a new Hyundai IONIQ 5.
               | 
               |  _In fact, many EV batteries may outlast the vehicles
               | they are installed in, then enjoy a second life in a
               | stationary storage application before finally being
               | recycled, according to EVANNEX._
               | 
               | "May", or may not. We don't know, because despite the
               | chatter, I'm not seeing this secondary car battery use.
               | Probably because no one replaces the batteries,
               | because...it's not worth it.
               | 
               |  _Can't speak to a Leaf, but I have fast DC charged my
               | 2018 Model S..._
               | 
               | Your Tesla also has the advantage of seven years of
               | battery advancement over our Leaf, which has degraded
               | 25%. And the Leaf battery thermal management is non-
               | existent. OTOH, as my wife and I push up against
               | retirement age, with a liquid-cooled battery pack and the
               | 12 years of learning about battery management, I'm
               | assuming that the battery in the new Ioniq 5 coming this
               | week will outlive us.
        
               | Dylan16807 wrote:
               | > That's because replacing the battery in a 2011 Nissan
               | Leaf will likely "total" the car (in that, the
               | replacement cost would be more than the car is worth).
               | 
               | Yeah, well, totalling shouldn't work like that. A car
               | with a new battery should be worth several thousand more,
               | and the totalling calculation for replacing the battery
               | should be based on the post-work value, not the pre-work
               | value.
        
               | belval wrote:
               | Yeah the Leaf ~2011 is infamous as an earlier "bad"
               | battery design so I wouldn't extrapolate too much from
               | it. The reality is also that as battery capacity
               | increases, people simply won't notice 10-15% degradation
               | of the pack because their commute is so much shorter than
               | the vehicule's range.
        
               | mikestew wrote:
               | And I'm not really extrapolating too much from it, as I
               | expect our soon-to-be-in-the-driveway Ioniq 5 to perform
               | much better (as in, outlives me). The Leaf was the first
               | mass-market electric car in, what, 100 years? Yeah, we
               | expected some early-adopter teething pains (including a
               | short-lived battery), and we have no complaints with the
               | OG Leaf, enough so that we swore off ICE vehicles years
               | ago and await our 2nd electric car.
               | 
               | But at the same time, it's a counter to _Nissan marketing
               | guy_ trying to mansplain to me about their battery
               | lifecycle. I own one of your batteries, Marketing Guy,
               | and I 'm detecting slight hints of marketing bullshit.
        
               | neuronexmachina wrote:
               | Is there a consumer market yet for buying/selling old EV
               | batteries for stationary storage? Some quick googling
               | isn't turning anything up.
        
               | myself248 wrote:
               | Batteryhookup and Jag35 are hobbyist-friendly places
               | dealing in such things. Safety or documentation are very
               | much YOYOMF.
        
               | mardifoufs wrote:
               | I can vouch for battery hookup, they even sell new/never
               | used overstock sometimes. Pretty good way to build your
               | own battery back up system, which has helped me a lot
               | when we lost power here in quebec for 4 days last week.
        
               | outworlder wrote:
               | Probably not at scale due to all the different form
               | factors. There are plenty of hobbyists doing that,
               | however.
        
               | rootusrootus wrote:
               | You can buy old Tesla modules (typically from wrecked
               | cars) on eBay. Once in a while I see people on the RV
               | forums use them instead of LFP, though honestly I'd much
               | rather have LFP for RV or home energy storage than
               | regular lithium ion.
        
           | acyou wrote:
           | Yes, vehicle batteries and stationary storage are used in
           | much more "forgiving" environments than laptops and power
           | tools, when it comes to cell life. Lower power draw, better
           | battery management systems, less temperature fluctuation,
           | less physical impact.
           | 
           | Battery production is still massively wasteful in terms of
           | partially finished or finished products that need to be
           | scrapped. The reason is that battery quality is _critical at
           | every level_. One tiny piece of iron embedded in one battery
           | out of a million can mean a catastrophic fire and tens of
           | millions in damages. If there is a systemic defect that
           | manifests during cell testing and is caught, the whole
           | production batch should be scrapped. Most of this scrap
           | happens before the batteries are shipped, and you never see
           | it, except in this too-honest article. You see how this plays
           | out in car fires, resulting from battery defects, resulting
           | in large recalls.
           | 
           | Run into defects in semiconductor manufacturing, and scrap
           | cost is lower, and you don't have an obvious and direct link
           | between the defects and catastrophic failure modes.
           | 
           | Keeping iron particles and manufacturing defects out of
           | batteries isn't a "solvable" problem. You try to minimize it
           | and catch it. Without technical breakthroughs and using
           | existing technologies, the higher the batteries' performance,
           | the less the margin for error.
           | 
           | We don't have a good baseline cultural understanding for what
           | lithium-ion batteries are. In general, household batteries,
           | AAs, AAAs, car batteries use a water-based electrolyte. They
           | do not catch fire. Lithium-ion batteries use an organic
           | solvent as electrolyte and when punctured, dropped, or just
           | cycling in everyday use if defective, turn into red-hot self-
           | propelled blowtorches.
        
           | londons_explore wrote:
           | > stationary storage that will eventually EOL
           | 
           | I suspect stationary storage will never EOL. Even after tens
           | of thousands of recharge cycles, the battery can still store
           | _some_ energy, perhaps just 10% of the design capacity, but
           | thats still worth something so it 's still worth running.
           | 
           | The only time it is worth throwing out is if the land is
           | valuable and you need it for another project.
           | 
           | This does depend on there not being much 'parasitic load' -
           | ie. fans and pumps which run 24x7 which cost money to run
           | even when they aren't really needed when the battery capacity
           | and charge/discharge speed is really low.
        
             | peer2pay wrote:
             | Eh not sure about this one.
             | 
             | With SoH decreasing the internal resistance increases and
             | the battery inherently becomes a fire hazard. At some point
             | the energy required for cooling will not be justifiable and
             | the battery will have to be decommissioned.
        
               | londons_explore wrote:
               | As internal resistance rises, you just need to charge
               | slower...
               | 
               | A battery that normally takes an hour to charge can
               | charge 10x slower and take 10 hours to charge, and still
               | be providing some useful value. (nearly everywhere will
               | have a day/night power price discrepancy, as well as a
               | weekday vs weekend discrepancy, and a hot/cold weather
               | discrepancy - so there are lots of timescales over which
               | money can be made)
        
         | iseanstevens wrote:
         | I think this is the state of the art at scale currently.
         | 
         | I bet if you can execute better they would love to hire you! ;)
        
           | acyou wrote:
           | Yes, I think you're right that this is the state of the art
           | at scale.
           | 
           | I wish the article went into a little more detail on the
           | extent of technical achievement that was reached in
           | commissioning this facility. Never mind the core process, can
           | only imagine the scale of the fire suppression system, dust
           | and fume management, etc. It really is impressive. They
           | should publish a video tour.
           | 
           | I think that this recycling facility occupies a supply chain
           | niche in a larger system: Dispose of old battery cells and
           | preserve the rest of the materials as concentrated ores. The
           | existing cells cannot be safely warehoused as cells, due to
           | fire risk. The concentrated ores can be stored cheaply and
           | safely and will maintain a stable or increasing indexed
           | commodity value, proportionate to improvements in refining
           | processes.
           | 
           | I just think that getting the cell cores out intact and
           | separate from the steel casings would be a great start for
           | the subsequent materials separation processes. Imagine if the
           | cathode and anode foils could be further separated at the
           | time of cell disassembly, and you would have a few material
           | streams that would be simpler to process downstream: steel
           | casings contaminated with powder and maybe a little aluminum
           | and copper, cathode foils with the bulk of the cathode
           | powders and close to zero iron, anode foils with the bulk of
           | the anode powders and close to zero iron, and mixed powder
           | flakes with close to zero iron.
           | 
           | I guess it's about where you move cost and complexity. I view
           | the whole cell grinding as moving complexity downstream. Yes,
           | it may end up being the right thing to do, but that will
           | depend on future technological developments in metal
           | refining, hydrometallurgical separation, and other
           | techniques.
        
         | coryrc wrote:
         | Reduce, Reuse, Recycle
         | 
         | You seem upset that "reuse" is a different word than "recycle".
        
           | acyou wrote:
           | We may or may not develop processes to efficiently recycle
           | the "black mass". For now, these processes do not exist.
           | 
           | Battery recycling may go in a different direction than it's
           | currently heading. We may decide to focus on separating out
           | the most valuable of these elements, or only elements from
           | certain battery chemistries. We may even decide that it's not
           | feasible to chemically separate ground battery materials
           | containing iron, chromium, or other contaminants.
           | 
           | In the short term, re-using lithium-ion cells is not
           | particularly feasible due to issues with cell safety and
           | handling. In my mind, re-use doesn't enter into the
           | conversation. If cells are being decommissioned, they would
           | ideally be at or near the end of their useful lives anyways.
           | For instance, if a vehicle was in a car accident, you would
           | never re-use the cells, due to concerns about acceleration
           | damage.
        
             | coryrc wrote:
             | Re-use is happening all over. Used Nissan Leaf cells sell
             | for almost new prices. I wish it wasn't true because I'd
             | like a few packs myself.
        
           | bromuro wrote:
           | Recycling causes harm for the environment. It's not a viable
           | solution in the middle terms.
        
         | jabart wrote:
         | How do you think they get it out of the ground with all the
         | other contaminants? I'm making an educated guess that a
         | recycling business has figured out how to make it economical at
         | scale.
        
           | acyou wrote:
           | For each element, I believe there is a combination of
           | electrolysis, electrowinning, leaching and other
           | hydrometallurgical and refining processes that is used to
           | refine from ore into a pure state.
           | 
           | In the article, lithium is extracted from the recycled cell
           | materials. Relatively cheap lithium can be extracted because
           | it occupies position #3 in the periodic table and has very
           | different chemical properties than most of the other
           | elements. According to the article, the expensive elements,
           | occupying positions #24 through #30 in the periodic table,
           | are left together in the black mass and re-sold.
           | 
           | Separating elements #24 through #30 is not yet easy and
           | economical. The central challenges are: A. The elements are
           | all adjacent to one another in the periodic table B. The
           | finished outputs must be extremely pure in order to be
           | suitable for use in battery materials C. Centuries of
           | advancement in mining, metallurgical and process research and
           | development focuses (mostly) on how to get (mostly) pure
           | elements from ores
           | 
           | That's not to say we won't get there. I just think that
           | opening a cell grinding and breakdown facility isn't a
           | particularly large step in the right direction. I actually
           | think it may be a step in the wrong direction, and that cell
           | processing facilities should perhaps be focusing on
           | complexity at the cell disassembly level, processing
           | individual cells to mechanically separate elements, given
           | that cells enter recycling facilities as attached/assembled
           | but relatively nicely separated casings, cathode and anode
           | foils, and cathode and anode powders.
           | 
           | If there are large subsequent advancements in chemical
           | refining processes for separating elements #24 through #30,
           | my above assessments will be proven wrong.
        
         | ZeroGravitas wrote:
         | You seem to be adding some details not in the article. Are you
         | familiar with them?
         | 
         | > Currently, Ascend sells most of these substances to the
         | market;
         | 
         | I took that line to mean they sell the recycled materials. You
         | seem to think they are storing them as a combined goop.
        
           | acyou wrote:
           | I do have a little familiarity with lithium-ion technologies,
           | but no direct insight into battery recycling. Please correct
           | me if I'm mistaken.
           | 
           | I absolutely do think that "recycled" battery materials are
           | being stored as combined goop or "black mass"! For the
           | following reasons: 1. I'm not aware of a commodity spot price
           | for battery sludge/powder 2. I'm not aware of any cell
           | manufacturer using recycled materials in their cathode
           | materials 3. I'm not aware of any cell manufacturer or
           | recycler processing recycled battery sludge/powder and re-
           | selling cathode materials made from recycled materials 4. I
           | am well aware of the large technical and cost barrier to
           | processing and separating this "black mass": The chemical
           | elements occupy all of the positions from #24-#30 in the
           | periodic table, and existing processes to separate the
           | elements are expensive and resource-intensive.
           | 
           | What I don't have insight into is: who is buying recycled
           | battery material mixtures? If they are available cheaply, we
           | could speculate on them and hold them, assuming that refining
           | processes will grow cheaper over time, and that the value of
           | the recycled material mixtures will increase.
        
             | ZeroGravitas wrote:
             | Their website seems to be claiming they have some secret
             | sauce:
             | 
             | > Our advantage starts with a remarkable innovation: Other
             | processes leach metals out of spent battery materials, but
             | our patented Hydro-to-Cathode direct precursor synthesis
             | process leaches out impurities, keeping the valuable metals
             | in solution and eliminating multiple steps in the recycling
             | flow.
        
         | londons_explore wrote:
         | I think the 'grind it up and use chemistry to extract the
         | valuable bits' is the future of recycling.
         | 
         | The reality is that lifespans of products is so long (eg. 30+
         | years) that no recycling process wants to be built to fit
         | standard mechanical designs from 30 years ago... and 20 years
         | ago... and 10 years ago... Multiply by the number of different
         | designs from different companies and different countries (even
         | with regulation, it is unlikely we would get one global
         | mechanically recyclable design).
         | 
         | If process chemists can't extract everything, then you plasma-
         | ionize what's left and now you just have plain old elements to
         | deal with.
        
           | acyou wrote:
           | Chromium, manganese, iron, cobalt, nickel, copper and zinc
           | are elements # 24, 25, 26, 27, 28, 29, 30. The processes to
           | separate them are currently resource-intensive and expensive.
           | They need to be separated by conventional smelting and
           | refining processes or hydro metallurgical processes, or some
           | combination. These processes need to do a great job of
           | purification for the materials to be battery grade.
           | 
           | Plasma ionization, can it be cheap and scalable?
        
           | makerdiety wrote:
           | > I think the 'grind it up and use chemistry to extract the
           | valuable bits' is the future of recycling. [...] If process
           | chemists can't extract everything, then you plasma-ionize
           | what's left and now you just have plain old elements to deal
           | with.
           | 
           | So high temperature applications which remove strong bonds
           | and create programmable ions can lead to atomic elements?
        
           | londons_explore wrote:
           | steel recycling has the same concern.
           | 
           | Sure, you can rip apart a building and say "ooh, thats a nice
           | steel beam - we could reuse that for another building, or cut
           | it into sheets to roll flat into something else"... But it is
           | cheaper and easier just to chuck it into a furnace and melt
           | it down and start from scratch.
        
             | acyou wrote:
             | This is the correct way of thinking, and is widely
             | applicable to many commonly recycled materials. Wood,
             | aluminum, steel, and some plastics can be efficiently
             | processed in this way.
             | 
             | Battery materials and applications are different. They
             | cannot be cheaply and easily melted down and re-used. The
             | main constituents are all very similar and difficult to
             | separate, and need to be separated extremely well in order
             | to be used in battery applications.
             | 
             | The lithium carbonate extraction is very telling. Lithium
             | is #3 in the periodic table. The remaining elements that we
             | would want to extract occupy every number from #24 through
             | #30. The reason that they are extracting cheap lithium and
             | none of the heavy, expensive elements, is that more process
             | development needs to be done.
             | 
             | In light of the above, creating a facility to grind up
             | batteries does not represent much progress towards the core
             | problem, and is not a particularly large step in the right
             | direction. It would be like making a facility to grind up
             | plastic, without having a process in place to recycle the
             | plastic. It's great, but you need more, much more.
        
             | jgtrosh wrote:
             | But that's not the same, the above process would be like
             | melting the steel and glass and concrete from the building
             | and hope future chemistry allows us to separate them
        
               | rimunroe wrote:
               | I'm not a chemist, but this is something we're already
               | very good at, and have been for quite some time. Silicon
               | oxides occur very commonly in iron ores, and are a major
               | component of slag.
        
               | WJW wrote:
               | Current chemistry allows us to do that just fine. Glass
               | melts at a much lower temperature and is much less dense
               | than steel. Concrete is not as dense as steel, but melts
               | at a much higher temperature. So, if you heat up the
               | whole mixture to steel melting temperatures, the glass
               | and steel will melt and can be poured off, while the
               | concrete will stay solid. Then the molten mixture of
               | steel and glass will naturally separate because the steel
               | part is so much heavier than the glass part and they
               | don't naturally mix all that well.
               | 
               | (Fun fact, glass pane manufacturing is often done by
               | floating the molten glass on a bath of molten metal so
               | that the surface tension will make it flat. AFAIK they
               | don't usually use molten steel as the metal though.)
        
               | jopsen wrote:
               | But if you can pull out the steel beams without all the
               | concrete, melting it will be a lot cheaper.
               | 
               | Imagine grinding up a bridge or tunnel and trying melt
               | all the steel out of the concrete.
               | 
               | That sounds expensive.
        
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