[HN Gopher] Panel with photovoltaic material layered on silicon ...
       ___________________________________________________________________
        
       Panel with photovoltaic material layered on silicon hits 33%
       efficiencies
        
       Author : mfiguiere
       Score  : 79 points
       Date   : 2023-07-07 18:06 UTC (1 days ago)
        
 (HTM) web link (arstechnica.com)
 (TXT) w3m dump (arstechnica.com)
        
       | throwawaymaths wrote:
       | We should all take a moment and appreciate that plants are pegged
       | to (IIRC) 10-15% theoretical max efficiency, and that's just in
       | photocapture, it's even worse when you factor in chemical
       | inefficies in storage and conversion of sugars back to usable atp
       | (which it must do to use the energy)
        
         | nightfly wrote:
         | Plants also are able to make more of themselves from dirt out
         | of pennies worth of matterial
        
           | ben_w wrote:
           | Mostly they make themselves out of air, which is even better.
           | 
           | The dirt has necessary trace elements, but the carbon? That's
           | all from CO2.
        
             | [deleted]
        
             | throwawaymaths wrote:
             | Oh man you've never cared for trees/plants have you. Some
             | of em (most often the ones you "want") are total crybabies
             | over those "trace elements".
             | 
             | You can't have DNA without phosphorus, for example, and
             | many plants can't make nitrogen from air. Don't get me
             | started on magnesium (needed for chlorophyll)
        
               | chewbacha wrote:
               | I understand what you mean but the vast majority of their
               | structure is carbon based and that comes from gaseous
               | CO2. Can't survive without the dirt but can't get big
               | without CO2
        
               | TaylorAlexander wrote:
               | I want to suggest re-reading their comment. "mostly they
               | make themselves from air" and "dirt has necessary trace
               | elements" are both 100% factually correct. The word
               | "necessary" covers what you are saying in your comment.
               | There's no need to suggest they haven't raised plants
               | when what they said is literally correct.
        
               | sbierwagen wrote:
               | https://nutrients.ifas.ufl.edu/nutrient_pages/bsfpages/Es
               | sen...                   element     %, dry wt.
               | oxygen      45         carbon      44         hydrogen
               | 6.3         nitrogen    1.3         silicon     1.2
               | potassium   0.9         calcium     0.25
               | phosphorus  0.16         magnesium   0.16         sulfur
               | 0.15         chlorine    0.15         aluminum    0.11
               | sodium      0.03         iron        0.009
               | manganese   0.006         zinc        0.003         boron
               | 0.001         copper      0.0005         molybdenum
               | 0.0001
               | 
               | Just CHON is 96.6% of plant mass. Adding silicon,
               | potassium and calcium brings it up to 98.95%
        
               | kccqzy wrote:
               | What's your point? If I only allow you to eat C, H, O, N
               | and their compounds, will you survive?
        
             | goldenkey wrote:
             | In the same vein, most of our energy comes from oxygen, not
             | the food we eat :-)
             | 
             | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6379287/
        
               | detourdog wrote:
               | Yikes sounds like decomposition.
        
         | londons_explore wrote:
         | It's kinda surprising that plant efficiency is so low,
         | considering the absolutely massive number of plants and the
         | hundreds of millions of years of competitive evolution to
         | collect as much energy from sunlight as possible.
        
           | api wrote:
           | Other limiting resources dominate over energy availability
           | for plants.
        
           | nightfly wrote:
           | I think they just don't have any need/pressure to be more
           | efficient than that
        
             | londons_explore wrote:
             | If you can collect more carbon, you can grow faster,
             | letting you put big leaves to collect more light and
             | overshadow and kill all the plants below you.
             | 
             | Being a plant is, locally, a winner-takes-all market.
        
         | londons_explore wrote:
         | > plants are pegged to (IIRC) 10-15% theoretical max efficiency
         | 
         | I suspect this is soon to change.... With CO2 levels around 280
         | ppm, the biggest challenge for many plants is finding a carbon
         | atom - in fact, many plants grow just as fast under just 10%
         | brightness sunlight.
         | 
         | Now that CO2 is up at 420 ppm, it's far easier to find carbon,
         | so now the evolutionary race will be on to collect more
         | sunlight and grow faster. And plants have done this before, ~20
         | million years ago, so somewhere there are probably some
         | recessive genes just waiting for their moment to shine again,
         | and natural selection will make them spread like wildfire.
        
           | ink_13 wrote:
           | "Soon" on an evolutionary scale could still mean hundreds if
           | not thousands of years.
           | 
           | For example, wood is a great food resource for fungi, but it
           | took millions of years for wood-eating fungi to evolve after
           | wood.
        
           | c_crank wrote:
           | It's good news for maize. That's a very carbon hungry crop.
        
           | c2h5oh wrote:
           | If it was just CO2 levels going up then maybe. The problem is
           | that temperatures are going up too, so gas solubility is
           | going down. This means that C4 or CAM photosynthesis plants
           | might get an edge over C3 on a larger area.
        
             | ChatGTP wrote:
             | We'd have to assume that due to the greenhouse effect , the
             | earth was also hotter then ?
        
           | timmg wrote:
           | Even without any genetic adaptations (probably?) the world is
           | "greening" due to increased CO2:
           | https://www.nasa.gov/feature/goddard/2016/carbon-dioxide-
           | fer...
        
       | mehdix wrote:
       | It'd be in user's best interest but not corporation's best
       | interest.
        
       | syntaxing wrote:
       | Does 33% efficiency means it can generate 3.3kW per m^2?!
        
         | philipkglass wrote:
         | 330 watts. Sunlight is about 1000 watts per square meter at
         | noon on a clear day.
        
       | hesdeadjim wrote:
       | Anyone know what the state of the art is/will be for panel
       | lifetimes? Efficiency is great, but I'd sacrifice some if it
       | meant 50+ year lifetimes of 85%+ peak output.
        
         | greenthrow wrote:
         | They essentially last 50+ years now, and have always, barring
         | damage. State of the art panels today warranty 90%+ output
         | after 25 years. So they probably aren't far off what you're
         | asking for at 50. They keep getting better and cheaper every
         | year.
        
           | jeffbee wrote:
           | NREL's latest data is summarized here:
           | 
           | https://www.nrel.gov/docs/fy22osti/81172.pdf#page=5
           | 
           | Some types of panels have increased capacity after being in
           | the field for years. Degradation is not a significant
           | economic concern at this stage of the process.
        
             | abdullahkhalids wrote:
             | I see degradation numbers between -0.1%/year and
             | -1.1%/year.
             | 
             | This translates to about
             | 
             | * 0.999^25 = 97.5% to 0.989^25 = 75.8% output after 25
             | years.
             | 
             | * 0.999^50 = 95% to 0.989^50 = 57.5% output after 50 years.
        
               | Retric wrote:
               | Data I've see doesn't show output dropping continuously
               | at a constant rate. Also some panels did show modest
               | improvement for a few years.
        
               | londons_explore wrote:
               | > modest improvement for a few years.
               | 
               | Many regions of the world are getting dryer. You might
               | just be seeing a global warming side effect as there is
               | less cloud cover.
        
               | londons_explore wrote:
               | It would be good to break the figures down between:
               | 
               | * The actual silicon is degrading
               | 
               | * The cover glass is getting
               | dirty/frosted/delaminating/optical adhesive is no longer
               | clear
               | 
               | * Electrical failure of a whole cell - for example it is
               | cracked, yet the panel still appears to work due to the
               | bypass diodes removing a whole cell from the circuit.
               | 
               | Sure - from the users point of view it doesn't matter,
               | but from an engineering point of view, the cause of
               | failure gives some clues how to prevent it.
        
           | philipkglass wrote:
           | This is true for panels on the market now, and most of those
           | produced in the past. The 33% tandem systems reported on by
           | Ars Technica see severe efficiency degradation after just a
           | few hundred hours of full-power operation, so that's
           | something that needs to be solved before perovskite-on-
           | silicon tandem systems enter mass production.
        
           | larsiusprime wrote:
           | What about hail damage? That's the main concern holding me
           | back, but is this something already being addressed?
        
             | abdullahkhalids wrote:
             | You can always put more/stronger glass on top to protect
             | them more.
             | 
             | But I would bet it is cheaper to buy insurance for such
             | infrequent events.
        
             | jackmott42 wrote:
             | Consumer panels on homes have hail protection since
             | forever.
        
             | ben_w wrote:
             | That sounds like you want armoured panels; As I understand
             | it, the degradation being discussed here is from the light
             | itself.
        
             | greenthrow wrote:
             | Most panel warranties cover hail up to like 1" diameter.
             | So, pretty sizable. Beyond that, you need insurance.
        
             | goldenkey wrote:
             | Is it possible to put some translucent protective material
             | that doesn't block the frequencies the panels absorb?
        
               | jackmott42 wrote:
               | yes, they use this new tech called glass.
        
         | epolanski wrote:
         | I have worked as a solar scientist researcher for some time,
         | have coauthored 3 papers in Michael Graetzel[1]'s laboratory
         | and I have some experience in both Graetzel cells and
         | perovskite solutions like the one mentioned in this article.
         | 
         | Long story short: scientific researchers, especially those in
         | well funded laboratories are incentivized by the wrong metrics
         | (in all fields, not unique to solar) and in this field the only
         | metric that matters is efficiency. It doesn't matter if your
         | cell decays by 50% in a day, it reached some great potential in
         | a new way, here's the way for a high impact publication.
         | 
         | Want to work on the other problem though? Lifetime, resiliency?
         | Cheap and affordable and non-toxic materials?
         | 
         | Good luck getting proper funding and exposure. Why? Because
         | scientific papers are a closed mafia, where a set of the most
         | influential scientists (doesn't matter how many scientists the
         | planet has, the moment you start entering a niche the number of
         | people is very low) in their field review the submitted papers.
         | Don't have high efficiency or you're not breaking science?
         | Forget a high-impact journal. You're back at B-tier, C-tier
         | papers, but those won't get you funding and status. Not great
         | for your career.
         | 
         | So what do you do? You play fool and focus your efforts and
         | many many millions of euros to get the next perovskite cell
         | that can reach high 20%s with some twist at least or go for the
         | 30%+ ones.
         | 
         | Just to express how sad and toxic the world of scientific
         | research is (not even mentioning the insane amount of fake data
         | that gets published every day, the politics, etc): instead of
         | being a researcher I now prefer being a web developer writing
         | forms list and tables.
         | 
         | [1] https://en.wikipedia.org/wiki/Michael_Gr%C3%A4tzel
        
           | casparvitch wrote:
           | I disagree that science has the wrong incentives. The place
           | for science is to chase new (e.g.) physics, not build
           | something useful.
           | 
           | As a society we have decided that (e.g.) physics should/shall
           | solve our problems with better technology. But that is not
           | what pure academic science is about, or what pure academic
           | scientists care about.
           | 
           | You want to iteratively improve technologies? Give more
           | funding to proper engineers, not physicists/chemists, even if
           | they're sometimes in the 'school of electrical engineering'.
        
             | ScoobleDoodle wrote:
             | Lifetime, resiliency, non-toxic structure are different
             | dimensions to efficiency and there are likely trade offs
             | between them. Those all can involve what you call "new
             | physics" but parent points out only one gets funding:
             | efficiency. Which parent also points out is suboptimal for
             | society.
        
               | jackmott42 wrote:
               | Parent claimed only one gets funding, but that is wrong.
               | Industry, capitalist companies work on the other stuff
               | all the time. Parent is likely wrong about researchers
               | not getting funding for that other stuff also, parent
               | likely had trouble getting funding himself due to bad
               | attitude and blames it on other factors.
        
               | epolanski wrote:
               | I like how you decided to trash years of my life and
               | experience and made up a scenario where I'm motivated by
               | envy or failure (and even faulty of bad attitude) behind
               | your keyboard because my experience doesn't fit your
               | views.
               | 
               | If you've been in this field, I'll gladly listen to your
               | experience.
        
           | philipkglass wrote:
           | Crystalline silicon cells are already cheap, non-toxic, and
           | long-lived. So it makes sense that most researchers are
           | looking for higher efficiency. Back when purified silicon
           | prices spiked around 2007-2008 there were a lot of efforts
           | looking into more affordable (if less efficient) thin film
           | based materials, but those fizzled out as wafered silicon got
           | cheap again and kept widening the efficiency gap over e.g.
           | amorphous silicon.
           | 
           | Since there's also a much bigger solar industry today than in
           | 2007, you also see more practically-minded research coming
           | out of corporate centers (e.g. Longi, Oxford PV, GCL System
           | Integration, and others working on perovskite cells and
           | perovskite-silicon tandems). Since they care about shipping
           | working products, they are focused on solving lifetime and
           | durability issues. Of course since this research can give a
           | big commercial edge as single junction silicon reaches its
           | efficiency limits, you'll also only see the really promising
           | work published after it is patented.
        
             | epolanski wrote:
             | Silicon is far from non-toxic to produce (requires insane
             | amount of heat and chemicals to be purified) and dispose.
        
               | fsh wrote:
               | Could you list some of these chemicals? A quick google
               | search only came up with pretty benign standard
               | industrial chemicals. Disposal is a complete non-issue
               | since the cells are inert and non-toxic (though recycling
               | probably makes more sense than dumping them somewhere).
        
               | jeffbee wrote:
               | All these factors are reflected in the price and yet
               | ordinary silicon PV panels are still dominating the
               | market.
        
         | ZeroGravitas wrote:
         | I'm the opposite, I'd trade some of the current longevity, for
         | ever increasing efficiency.
         | 
         | Some research suggests you should replace all solar panels
         | every 17 years because the tech will have advanced enough to
         | make it worthwile.
        
         | walrus01 wrote:
         | There are very reputable manufacturers now that warranty on a
         | sliding scale over time to be 84% of original STC watt rating
         | at 25 years.
        
       ___________________________________________________________________
       (page generated 2023-07-08 23:00 UTC)